Titanium, trichlorocyclopentadienyl-
- Formula: C5H5Cl3Ti
- Molecular weight: 219.319
- IUPAC Standard InChI: InChI=1S/C5H5.3ClH.Ti/c1-2-4-5-3-1;;;;/h1-5H;3*1H;/q;;;;+3/p-3
- IUPAC Standard InChIKey: AENCLWKVWIIOQH-UHFFFAOYSA-K
- CAS Registry Number: 1270-98-0
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: η5-Cyclopentadienyltitanium trichloride; Cyclopentadienyltitanium trichloride; π-Cyclopentadienyltitanium trichloride; Cyclopentadiene titanium trichloride; Cyclopentadienyltrichlorotitanium; Titanium, trichloro(η5-2,4-cyclopentadien-1-yl)-; Titanium, trichloro-π-cyclopentadienyl-; Trichloro(cyclopentadienyl)titanium; Trichloro-π-cyclopentadienyltitanium; Cyclopentadienyltitanium(IV) trichloride; Trichloro(cyclopentyldienyl)titanium
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 104.6 ± 8.4 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Tel'noi and Rabinovich, 1977.; AC |
| ΔsubH° | 89.1 ± 0.8 | kJ/mol | CC-SB | Balducci, Bardi, et al., 1977 | MS |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 89.8 | 379. | A | Stephenson and Malanowski, 1987 | Based on data from 354. to 404. K.; AC |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B.,
Thermochemistry of organic compounds of transition metals,
Usp. Khim., 1977, 46, 8, 1337. [all data]
Balducci, Bardi, et al., 1977
Balducci, G.; Bardi, G.; de Maria, G.; Gigli, R.,
VII All-Union Calorimetry Conference, Moscow, 1977. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Notes
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- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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