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Methylacrylonitrile

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

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Individual Reactions

C4H4N- + Hydrogen cation = Methylacrylonitrile

By formula: C4H4N- + H+ = C4H5N

Quantity Value Units Method Reference Comment
Deltar1551. ± 8.8kJ/molG+TSBartmess and Burnham, 1984gas phase; value altered from reference due to change in acidity scale
Quantity Value Units Method Reference Comment
Deltar1523. ± 8.4kJ/molIMREBartmess and Burnham, 1984gas phase; value altered from reference due to change in acidity scale

(CAS Reg. No. 42117-14-6 bullet 4294967295Methylacrylonitrile) + Methylacrylonitrile = CAS Reg. No. 42117-14-6

By formula: (CAS Reg. No. 42117-14-6 bullet 4294967295C4H5N) + C4H5N = CAS Reg. No. 42117-14-6

Quantity Value Units Method Reference Comment
Deltar212. ± 10.kJ/molN/ABartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bartmess and Burnham, 1984
Bartmess, J.E.; Burnham, R., Effect of central substituents on the gas phase acidities of propenes, J. Org. Chem., 1984, 49, 1382. [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]


Notes

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