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Gas Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 6000.
A 62.88678
B -2.292034
C 1.518324
D -0.155889
E -0.664449
F 615.0815
G 340.8504
H 635.9680
ReferenceChase, 1998
Comment Data last reviewed in March, 1967
Temperature
(K)
Cp
(J/mol*K)

(J/mol*K)
-(G° - H°298.15)/T
(J/mol*K)
H° - H°298.15
(kJ/mol)
298.54.85267.8267.9-0.01
300.54.95268.2267.90.10
400.58.05284.5270.15.78
500.59.44297.6274.311.66
600.60.18308.5279.117.64
700.60.62317.8284.023.69
800.60.91326.0288.829.76
900.61.12333.1293.335.86
1000.61.29339.6297.641.99
1100.61.45345.4301.748.12
1200.61.59350.8305.654.27
1300.61.74355.7309.260.44
1400.61.89360.3312.766.62
1500.62.04364.6316.072.82
1600.62.21368.6319.279.03
1700.62.38372.4322.285.26
1800.62.57375.9325.191.51
1900.62.76379.3327.997.77
2000.62.96382.6330.5104.1
2100.63.17385.6333.1110.4
2200.63.40388.6335.5116.7
2300.63.62391.4337.9123.0
2400.63.86394.1340.2129.4
2500.64.10396.7342.4135.8
2600.64.35399.2344.5142.2
2700.64.61401.7346.6148.7
2800.64.87404.0348.6155.2
2900.65.13406.3350.6161.7
3000.65.39408.5352.5168.2
3100.65.66410.7354.3174.7
3200.65.93412.8356.1181.3
3300.66.19414.8357.9187.9
3400.66.46416.8359.6194.6
3500.66.73418.7361.2201.2
3600.66.99420.6362.8207.9
3700.67.25422.4364.4214.6
3800.67.50424.2366.0221.4
3900.67.75426.0367.5228.1
4000.67.99427.7369.0234.9
4100.68.23429.4370.4241.7
4200.68.46431.0371.9248.5
4300.68.67432.6373.2255.4
4400.68.88434.2374.6262.3
4500.69.08435.8376.0269.2
4600.69.27437.3377.3276.1
4700.69.44438.8378.6283.0
4800.69.60440.3379.8290.0
4900.69.74441.7381.1297.0
5000.69.87443.1382.3303.9
5100.69.98444.5383.5310.9
5200.70.08445.8384.7317.9
5300.70.16447.2385.9324.9
5400.70.21448.5387.0332.0
5500.70.25449.8388.1339.0
5600.70.27451.0389.3346.0
5700.70.26452.3390.4353.0
5800.70.23453.5391.4360.1
5900.70.18454.7392.5367.1
6000.70.10455.9393.5374.1

References

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Gas Phase Heat Capacity (Shomate Equation), References