Ozone anion
- Formula: O3-
- Molecular weight: 47.9987
- CAS Registry Number: 12596-80-4
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Individual Reactions
By formula: O3- + N2 = (O3- • N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.3 ± 0.84 | kJ/mol | TDAs | Hiraoka, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.0 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -11.7 ± 2.1 | kJ/mol | TDAs | Hiraoka, 1988 | gas phase; B |
By formula: O3- + O2 = (O3- • O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.79 ± 0.84 | kJ/mol | TDAs | Hiraoka, 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.5 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | -15.1 ± 2.1 | kJ/mol | TDAs | Hiraoka, 1988 | gas phase; B |
By formula: (O3- • 4O2) + O2 = (O3- • 5O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.44 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; ΔrH, ΔrS approximate; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 68.6 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; ΔrH, ΔrS approximate; M |
By formula: (O3- • 2N2) + N2 = (O3- • 3N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.6 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.4 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 2O2) + O2 = (O3- • 3O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8. ± 1. | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 83.7 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 3N2) + N2 = (O3- • 4N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.5 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84.5 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 3O2) + O2 = (O3- • 4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 64.4 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 4N2) + N2 = (O3- • 5N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.6 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 78.2 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 5N2) + N2 = (O3- • 6N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.2 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.5 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 6N2) + N2 = (O3- • 7N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.6 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 76.1 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 7N2) + N2 = (O3- • 8N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7. ± 1. | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 73.2 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 8N2) + N2 = (O3- • 9N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6. ± 2. | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 70.7 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • N2) + N2 = (O3- • 2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 11.0 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 82.0 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • O2) + O2 = (O3- • 2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 8.5 ± 0.8 | kJ/mol | PHPMS | Hiraoka, 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 81.2 | J/mol*K | PHPMS | Hiraoka, 1988 | gas phase; M |
By formula: (O3- • 2H2O) + H2O = (O3- • 3H2O)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
19. | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; M |
By formula: (O3- • H2O) + H2O = (O3- • 2H2O)
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
26. | 296. | FA | Fehsenfeld and Ferguson, 1974 | gas phase; M |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka, 1988
Hiraoka, K.,
Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria,
Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4
. [all data]
Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E.,
Laboratory studies of negative ion reactions with atmospheric trace constituents,
J. Chem. Phys., 1974, 61, 3181. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
T Temperature ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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