Ozone anion


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Quantity Value Units Method Reference Comment
Δfgas-14.610 ± 0.060kcal/molR-EANovich, Engelking, et al., 1979 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
Δr2.70 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr18.4cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-2.80 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

O3- + Oxygen = (O3- • Oxygen)

By formula: O3- + O2 = (O3- • O2)

Quantity Value Units Method Reference Comment
Δr2.10 ± 0.20kcal/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr-3.60 ± 0.50kcal/molTDAsHiraoka, 1988gas phase; B

(O3- • 4Oxygen) + Oxygen = (O3- • 5Oxygen)

By formula: (O3- • 4O2) + O2 = (O3- • 5O2)

Quantity Value Units Method Reference Comment
Δr1.54kcal/molPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
Δr16.4cal/mol*KPHPMSHiraoka, 1988gas phase; ΔrH, ΔrS approximate; M

(O3- • 2Nitrogen) + Nitrogen = (O3- • 3Nitrogen)

By formula: (O3- • 2N2) + N2 = (O3- • 3N2)

Quantity Value Units Method Reference Comment
Δr2.5 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Oxygen) + Oxygen = (O3- • 3Oxygen)

By formula: (O3- • 2O2) + O2 = (O3- • 3O2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr20.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Nitrogen) + Nitrogen = (O3- • 4Nitrogen)

By formula: (O3- • 3N2) + N2 = (O3- • 4N2)

Quantity Value Units Method Reference Comment
Δr2.3 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Oxygen) + Oxygen = (O3- • 4Oxygen)

By formula: (O3- • 3O2) + O2 = (O3- • 4O2)

Quantity Value Units Method Reference Comment
Δr1.6 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr15.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Nitrogen) + Nitrogen = (O3- • 5Nitrogen)

By formula: (O3- • 4N2) + N2 = (O3- • 5N2)

Quantity Value Units Method Reference Comment
Δr2.1 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr18.7cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 5Nitrogen) + Nitrogen = (O3- • 6Nitrogen)

By formula: (O3- • 5N2) + N2 = (O3- • 6N2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.0cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 6Nitrogen) + Nitrogen = (O3- • 7Nitrogen)

By formula: (O3- • 6N2) + N2 = (O3- • 7N2)

Quantity Value Units Method Reference Comment
Δr1.8 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr18.2cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 7Nitrogen) + Nitrogen = (O3- • 8Nitrogen)

By formula: (O3- • 7N2) + N2 = (O3- • 8N2)

Quantity Value Units Method Reference Comment
Δr1.7 ± 0.3kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr17.5cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 8Nitrogen) + Nitrogen = (O3- • 9Nitrogen)

By formula: (O3- • 8N2) + N2 = (O3- • 9N2)

Quantity Value Units Method Reference Comment
Δr1.5 ± 0.4kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr16.9cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • Nitrogen) + Nitrogen = (O3- • 2Nitrogen)

By formula: (O3- • N2) + N2 = (O3- • 2N2)

Quantity Value Units Method Reference Comment
Δr2.6 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.6cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • Oxygen) + Oxygen = (O3- • 2Oxygen)

By formula: (O3- • O2) + O2 = (O3- • 2O2)

Quantity Value Units Method Reference Comment
Δr2.0 ± 0.2kcal/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr19.4cal/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Water) + Water = (O3- • 3Water)

By formula: (O3- • 2H2O) + H2O = (O3- • 3H2O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
4.5296.FAFehsenfeld and Ferguson, 1974gas phase; M

(O3- • Water) + Water = (O3- • 2Water)

By formula: (O3- • H2O) + H2O = (O3- • 2H2O)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
6.2296.FAFehsenfeld and Ferguson, 1974gas phase; M

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Novich, Engelking, et al., 1979
Novich, S.E.; Engelking, P.C.; Jones, P.L.; Futrell, J.H.; Lineberger, W.C., Laser photoelectron, photodetachment, and photodestruction spectra of O3-, J. Chem. Phys., 1979, 70, 2652. [all data]

Hiraoka, 1988
Hiraoka, K., Determination of the Stabilities of O3-(N2)n, O3-(O2)n, and O4-(N2)n from Measurements of the Gas Phase Equilibria, Chem. Phys., 1988, 125, 2-3, 439, https://doi.org/10.1016/0301-0104(88)87096-4 . [all data]

Fehsenfeld and Ferguson, 1974
Fehsenfeld, F.C.; Ferguson, E.E., Laboratory studies of negative ion reactions with atmospheric trace constituents, J. Chem. Phys., 1974, 61, 3181. [all data]


Notes

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