Deuterium, deuteronated
- Formula: D3+
- Molecular weight: 6.0417567535
- CAS Registry Number: 12595-96-9
- Information on this page:
- Other data available:
- Options:
Ion clustering data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: D3+ + Ar = (D3+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 29.1 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 60.7 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • Ar) + Ar = (D3+ • 2Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.1 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 73.2 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 2Ar) + Ar = (D3+ • 3Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.6 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.0 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 3Ar) + Ar = (D3+ • 4Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.2 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 69.5 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 4Ar) + Ar = (D3+ • 5Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.5 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.8 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 5Ar) + Ar = (D3+ • 6Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.1 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.9 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 6Ar) + Ar = (D3+ • 7Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.5 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 105. | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: D3+ + D2 = (D3+ • D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. ± 1. | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 78.7 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • D2) + D2 = (D3+ • 2D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.6 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 74.9 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 2D2) + D2 = (D3+ • 3D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.0 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 83.7 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 3D2) + D2 = (D3+ • 4D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.7 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 76.1 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 4D2) + D2 = (D3+ • 5D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.6 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.9 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 5D2) + D2 = (D3+ • 6D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.3 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 91.2 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 6D2) + D2 = (D3+ • 7D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.8 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 53.6 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 7D2) + D2 = (D3+ • 8D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.4 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 64.0 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 8D2) + D2 = (D3+ • 9D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.0 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 81.2 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 9D2) + D2 = (D3+ • 10D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3. | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84. | J/mol*K | N/A | Hiraoka and Mori, 1989, 2 | gas phase; Entropy change calculated or estimated |
References
Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T.,
Isotope Effect and Nature of Bonding in the Cluster Ions H3+(Ar)n and D3+(Ar)n,
J. Chem. Phys., 1989, 91, 8, 4821, https://doi.org/10.1063/1.456720
. [all data]
Hiraoka and Mori, 1989, 2
Hiraoka, K.; Mori, T.,
Thermochemical Stabilities of D3+(D2)n with n = 1 - 10,
Chem. Phys. Lett., 1989, 157, 5, 467, https://doi.org/10.1016/0009-2614(89)87282-3
. [all data]
Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.