Deuterium, deuteronated
- Formula: D3+
- Molecular weight: 6.0417567535
- CAS Registry Number: 12595-96-9
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
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Individual Reactions
By formula: (D3+ • 9D2) + D2 = (D3+ • 10D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3. | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase; Entropy change calculated or estimated |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 84. | J/mol*K | N/A | Hiraoka and Mori, 1989 | gas phase; Entropy change calculated or estimated |
By formula: (D3+ • 2Ar) + Ar = (D3+ • 3Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 18.6 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 77.0 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 3Ar) + Ar = (D3+ • 4Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 10.2 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 69.5 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 4Ar) + Ar = (D3+ • 5Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.5 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 72.8 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 5Ar) + Ar = (D3+ • 6Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.1 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.9 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 6Ar) + Ar = (D3+ • 7Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.5 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 105. | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • Ar) + Ar = (D3+ • 2Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 20.1 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 73.2 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: (D3+ • 2D2) + D2 = (D3+ • 3D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.0 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 83.7 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 3D2) + D2 = (D3+ • 4D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.7 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 76.1 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 4D2) + D2 = (D3+ • 5D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.6 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 79.9 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 5D2) + D2 = (D3+ • 6D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 7.3 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 91.2 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 6D2) + D2 = (D3+ • 7D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.8 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 53.6 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 7D2) + D2 = (D3+ • 8D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.4 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 64.0 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • 8D2) + D2 = (D3+ • 9D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 3.0 ± 0.4 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 81.2 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: (D3+ • D2) + D2 = (D3+ • 2D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 14.6 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 74.9 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
By formula: D3+ + Ar = (D3+ • Ar)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 29.1 ± 0.8 | kJ/mol | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 60.7 | J/mol*K | PHPMS | Hiraoka and Mori, 1989, 2 | gas phase |
By formula: D3+ + D2 = (D3+ • D2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 30. ± 1. | kJ/mol | PHPMS | Hiraoka and Mori, 1989 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 78.7 | J/mol*K | PHPMS | Hiraoka and Mori, 1989 | gas phase |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka and Mori, 1989
Hiraoka, K.; Mori, T.,
Thermochemical Stabilities of D3+(D2)n with n = 1 - 10,
Chem. Phys. Lett., 1989, 157, 5, 467, https://doi.org/10.1016/0009-2614(89)87282-3
. [all data]
Hiraoka and Mori, 1989, 2
Hiraoka, K.; Mori, T.,
Isotope Effect and Nature of Bonding in the Cluster Ions H3+(Ar)n and D3+(Ar)n,
J. Chem. Phys., 1989, 91, 8, 4821, https://doi.org/10.1063/1.456720
. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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