sodium methanolate

• Formula: CH₃NaO
• Molecular weight: 54.0237
• IUPAC Standard InChI: InChI=1S/CH3O.Na/c1-2;/h1H3;/q-1;+1 Copy

  
• IUPAC Standard InChIKey: WQDUMFSSJAZKTM-UHFFFAOYSA-N Copy
• CAS Registry Number: 124-41-4
• Chemical structure:
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• Other names: Sodium methoxide
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• Information on this page:
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • References
  • Notes
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

 (cr) + ( • 552) (solution) =  (l) +  (cr)

By formula: CH₃NaO (cr) + (HCl • 552H₂O) (solution) = CH₄O (l) + ClNa (cr)

 (cr) +  (l) =  (cr) +  (l)

By formula: CH₃NaO (cr) + H₂O (l) = HNaO (cr) + CH₄O (l)

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Leal, Pires de Matos, et al., 1991
Leal, J.P.; Pires de Matos, A.; Martinho Simões, J.A., J. Organometal. Chem., 1991, 403, 1. [all data]

Grenier and Westrum, 1957
Grenier, G.; Westrum, E.F., Jr., The low temperature heat capacity and thermodynamic properties of sodium methoxide, J. Am. Chem. Soc., 1957, 79, 1802-1804. [all data]

Notes

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• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  S°solid,1 bar	Entropy of solid at standard conditions (1 bar)
  ΔfH°solid	Enthalpy of formation of solid at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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