SO2+


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O2S+ + Carbon dioxide = (O2S+ • Carbon dioxide)

By formula: O2S+ + CO2 = (O2S+ • CO2)

Quantity Value Units Method Reference Comment
Δr9.6 ± 0.2kcal/molDTIllies, 1988gas phase; ΔrH(0 K)=10.2 kcal/mol
Quantity Value Units Method Reference Comment
Δr16.5cal/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=10.2 kcal/mol

O2S+ + Krypton = (O2S+ • Krypton)

By formula: O2S+ + Kr = (O2S+ • Kr)

Quantity Value Units Method Reference Comment
Δr7.kcal/molPDissKim, Jarrold, et al., 1986gas phase; ΔrH<

O2S+ + Sulfur dioxide = (O2S+ • Sulfur dioxide)

By formula: O2S+ + O2S = (O2S+ • O2S)

Quantity Value Units Method Reference Comment
Δr15.2kcal/molPIErickson and Ng, 1981gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

O2S+ + Carbon dioxide = (O2S+ • Carbon dioxide)

By formula: O2S+ + CO2 = (O2S+ • CO2)

Quantity Value Units Method Reference Comment
Δr9.6 ± 0.2kcal/molDTIllies, 1988gas phase; ΔrH(0 K)=10.2 kcal/mol
Quantity Value Units Method Reference Comment
Δr16.5cal/mol*KDTIllies, 1988gas phase; ΔrH(0 K)=10.2 kcal/mol

O2S+ + Krypton = (O2S+ • Krypton)

By formula: O2S+ + Kr = (O2S+ • Kr)

Quantity Value Units Method Reference Comment
Δr7.kcal/molPDissKim, Jarrold, et al., 1986gas phase; ΔrH<

O2S+ + Sulfur dioxide = (O2S+ • Sulfur dioxide)

By formula: O2S+ + O2S = (O2S+ • O2S)

Quantity Value Units Method Reference Comment
Δr15.2kcal/molPIErickson and Ng, 1981gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Illies, 1988
Illies, A.J., Thermochemistry of the Gas - Phase Ion - Molecule Clustering of CO2+CO2, SO2+CO2, N2O+N2O, O2+CO2, NO+CO2 and NO+N2O: Description of a New Hybrid Drift Tube/Ion Source with Coaxial Electron Beam and Ion Exit Apertures, J. Phys. Chem., 1988, 92, 10, 2889, https://doi.org/10.1021/j100321a037 . [all data]

Kim, Jarrold, et al., 1986
Kim, H.S.; Jarrold, M.F.; Bowers, M.T., Photodissociation of Weakly Bound Ion-Molecule Clusters: Kr.SO2+, J. Chem. Phys., 1986, 90, 16, 3584, https://doi.org/10.1021/j100407a024 . [all data]

Erickson and Ng, 1981
Erickson, J.; Ng, C.Y., Molecular Beam Photoionization Study of SO2 and (SO2)2, J. Chem. Phys., 1981, 75, 4, 1650, https://doi.org/10.1063/1.442242 . [all data]


Notes

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