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Carbon dioxide

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Reaction thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 100

(Nitrogen oxide anion bullet 6Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 7Carbon dioxide)

By formula: (NO2- bullet 6CO2) + CO2 = (NO2- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar18. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-8.8 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet 7Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 8Carbon dioxide)

By formula: (NO2- bullet 7CO2) + CO2 = (NO2- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar18. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar-9.6 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

(Nitrogen oxide anion bullet Carbon dioxide) + Carbon dioxide = (Nitrogen oxide anion bullet 2Carbon dioxide)

By formula: (NO2- bullet CO2) + CO2 = (NO2- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar28. ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar4.2 ± 4.2kJ/molTDAsHiraoka and Yamabe, 1992gas phase; B

O3S- + Carbon dioxide = (O3S- bullet Carbon dioxide)

By formula: O3S- + CO2 = (O3S- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar27.2 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar86.6J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar1.3 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Sodium ion (1+) bullet Carbon dioxide) + Carbon dioxide = (Sodium ion (1+) bullet 2Carbon dioxide)

By formula: (Na+ bullet CO2) + CO2 = (Na+ bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar46.0kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
20.310.DTKeller and Beyer, 1971gas phase; low E/N; M

CN- + Carbon dioxide = (CN- bullet Carbon dioxide)

By formula: CN- + CO2 = (CN- bullet CO2)

Quantity Value Units Method Reference Comment
Deltar72.4 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar132.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar33.1 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B

(Nitric oxide anion bullet 5Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 6Carbon dioxide)

By formula: (NO- bullet 5CO2) + CO2 = (NO- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KN/AHiraoka and Yamabe, 1991gas phase; Entropy change calculated or estimated; M

(Fluorine anion bullet 6Carbon dioxide) + Carbon dioxide = (Fluorine anion bullet 7Carbon dioxide)

By formula: (F- bullet 6CO2) + CO2 = (F- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPHPMSHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KN/AHiraoka, Mizuse, et al., 1987gas phase; Entropy change calculated or estimated; M

(Formyl cation bullet 3Carbon dioxide) + Carbon dioxide = (Formyl cation bullet 4Carbon dioxide)

By formula: (CHO+ bullet 3CO2) + CO2 = (CHO+ bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar35.kJ/molPHPMSHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M

(CO3- bullet 6Carbon dioxide) + Carbon dioxide = (CO3- bullet 7Carbon dioxide)

By formula: (CO3- bullet 6CO2) + CO2 = (CO3- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar18.6kJ/molPHPMSHiraoka and Yamabe, 1992gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AHiraoka and Yamabe, 1992gas phase; Entropy change calculated or estimated; M

(CO2+ bullet 5Carbon dioxide) + Carbon dioxide = (CO2+ bullet 6Carbon dioxide)

By formula: (CO2+ bullet 5CO2) + CO2 = (CO2+ bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AHiraoka, Nakajima, et al., 1988gas phase; Entropy change calculated or estimated; M

(Oxygen cation bullet 5Carbon dioxide) + Carbon dioxide = (Oxygen cation bullet 6Carbon dioxide)

By formula: (O2+ bullet 5CO2) + CO2 = (O2+ bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AHiraoka, Nakajima, et al., 1988gas phase; Entropy change calculated or estimated; M

Cesium ion (1+) + Carbon dioxide = (Cesium ion (1+) bullet Carbon dioxide)

By formula: Cs+ + CO2 = (Cs+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar26.kJ/molDTMcKnight and Sawina, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.8J/mol*KDTMcKnight and Sawina, 1972gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
10.301.HPMSBanic and Iribarne, 1985gas phase; electric fields; M

Potassium ion (1+) + Carbon dioxide = (Potassium ion (1+) bullet Carbon dioxide)

By formula: K+ + CO2 = (K+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molHPMSCastleman and Keesee, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar63.6J/mol*KHPMSCastleman and Keesee, 1981gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.310.DTKeller and Beyer, 1971, 2gas phase; low E/N; M

(CHO2+ bullet 2Carbon dioxide) + Carbon dioxide = (CHO2+ bullet 3Carbon dioxide)

By formula: (CHO2+ bullet 2CO2) + CO2 = (CHO2+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar25.kJ/molPHPMSHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M

Tetrafluoromethane + 2Water = Carbon dioxide + 4hydrogen fluoride

By formula: CF4 + 2H2O = CO2 + 4HF

Quantity Value Units Method Reference Comment
Deltar-174. ± 4.2kJ/molCmGood, Scott, et al., 1956gas phase; HF has 10 moles H2O, see Scott, Good, et al., 1955; ALS
Deltar-174. ± 4.2kJ/molCmScott, Good, et al., 1955gas phase; Heat of hydrolysis; ALS

O2S+ + Carbon dioxide = (O2S+ bullet Carbon dioxide)

By formula: O2S+ + CO2 = (O2S+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar40. ± 0.8kJ/molDTIllies, 1988gas phase; «DELTA»rH(0 K)=42.7 kJ/mol; M
Quantity Value Units Method Reference Comment
Deltar69.0J/mol*KDTIllies, 1988gas phase; «DELTA»rH(0 K)=42.7 kJ/mol; M

Methyl cation + Carbon dioxide = (Methyl cation bullet Carbon dioxide)

By formula: CH3+ + CO2 = (CH3+ bullet CO2)

Quantity Value Units Method Reference Comment
Deltar207.kJ/molPHPMSMcMahon, Heinis, et al., 1988gas phase; switching reaction(CH3+)N2, Entropy change calculated or estimated, uses MCA(N2) = 202. kJ/mol; Foster, Williamson, et al., 1974; M

(Iodide bullet 10Carbon dioxide) + Carbon dioxide = (Iodide bullet 11Carbon dioxide)

By formula: (I- bullet 10CO2) + CO2 = (I- bullet 11CO2)

Quantity Value Units Method Reference Comment
Deltar4.2 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 11Carbon dioxide) + Carbon dioxide = (Iodide bullet 12Carbon dioxide)

By formula: (I- bullet 11CO2) + CO2 = (I- bullet 12CO2)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 12Carbon dioxide) + Carbon dioxide = (Iodide bullet 13Carbon dioxide)

By formula: (I- bullet 12CO2) + CO2 = (I- bullet 13CO2)

Quantity Value Units Method Reference Comment
Deltar4.6 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 10Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 11Carbon dioxide)

By formula: (Br- bullet 10CO2) + CO2 = (Br- bullet 11CO2)

Quantity Value Units Method Reference Comment
Deltar2. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 9Carbon dioxide) + Carbon dioxide = (Iodide bullet 10Carbon dioxide)

By formula: (I- bullet 9CO2) + CO2 = (I- bullet 10CO2)

Quantity Value Units Method Reference Comment
Deltar4. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 9Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 10Carbon dioxide)

By formula: (Br- bullet 9CO2) + CO2 = (Br- bullet 10CO2)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Iodide bullet 8Carbon dioxide) + Carbon dioxide = (Iodide bullet 9Carbon dioxide)

By formula: (I- bullet 8CO2) + CO2 = (I- bullet 9CO2)

Quantity Value Units Method Reference Comment
Deltar12. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 2Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 3Carbon dioxide)

By formula: (Br- bullet 2CO2) + CO2 = (Br- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar21. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 3Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 4Carbon dioxide)

By formula: (Br- bullet 3CO2) + CO2 = (Br- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar22. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 4Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 5Carbon dioxide)

By formula: (Br- bullet 4CO2) + CO2 = (Br- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar18. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 5Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 6Carbon dioxide)

By formula: (Br- bullet 5CO2) + CO2 = (Br- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar17. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 6Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 7Carbon dioxide)

By formula: (Br- bullet 6CO2) + CO2 = (Br- bullet 7CO2)

Quantity Value Units Method Reference Comment
Deltar15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 7Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 8Carbon dioxide)

By formula: (Br- bullet 7CO2) + CO2 = (Br- bullet 8CO2)

Quantity Value Units Method Reference Comment
Deltar15. ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

(Bromine anion bullet 8Carbon dioxide) + Carbon dioxide = (Bromine anion bullet 9Carbon dioxide)

By formula: (Br- bullet 8CO2) + CO2 = (Br- bullet 9CO2)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 8.4kJ/molPDisArnold, Bradforth, et al., 1995gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B

Carbon dioxide + Carbon Tetrachloride = 2Phosgene

By formula: CO2 + CCl4 = 2CCl2O

Quantity Value Units Method Reference Comment
Deltar70. ± 2.kJ/molEqkLord and Pritchard, 1969gas phase; Two values for Hf; ALS
Deltar70. ± 2.kJ/molEqkLord and Pritchard, 1969gas phase; Two values for Hf; ALS

(Sodium ion (1+) bullet 2Water) + Carbon dioxide = (Sodium ion (1+) bullet Carbon dioxide bullet 2Water)

By formula: (Na+ bullet 2H2O) + CO2 = (Na+ bullet CO2 bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Nitric oxide anion bullet 2Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 3Carbon dioxide)

By formula: (NO- bullet 2CO2) + CO2 = (NO- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar30. ± 2.kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Nitric oxide anion bullet 3Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 4Carbon dioxide)

By formula: (NO- bullet 3CO2) + CO2 = (NO- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar24. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.9J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Nitric oxide anion bullet 4Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 5Carbon dioxide)

By formula: (NO- bullet 4CO2) + CO2 = (NO- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar22. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(Sodium ion (1+) bullet Water) + Carbon dioxide = (Sodium ion (1+) bullet Carbon dioxide bullet Water)

By formula: (Na+ bullet H2O) + CO2 = (Na+ bullet CO2 bullet H2O)

Quantity Value Units Method Reference Comment
Deltar52.7kJ/molHPMSPeterson, Mark, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KHPMSPeterson, Mark, et al., 1984gas phase; M

(Nitric oxide anion bullet Carbon dioxide) + Carbon dioxide = (Nitric oxide anion bullet 2Carbon dioxide)

By formula: (NO- bullet CO2) + CO2 = (NO- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar31. ± 2.kJ/molPHPMSHiraoka and Yamabe, 1991gas phase; M
Quantity Value Units Method Reference Comment
Deltar71.5J/mol*KPHPMSHiraoka and Yamabe, 1991gas phase; M

(CO3- bullet 2Carbon dioxide) + Carbon dioxide = (CO3- bullet 3Carbon dioxide)

By formula: (CO3- bullet 2CO2) + CO2 = (CO3- bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar23.0 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(CO3- bullet 3Carbon dioxide) + Carbon dioxide = (CO3- bullet 4Carbon dioxide)

By formula: (CO3- bullet 3CO2) + CO2 = (CO3- bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar21.8 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(CO3- bullet 4Carbon dioxide) + Carbon dioxide = (CO3- bullet 5Carbon dioxide)

By formula: (CO3- bullet 4CO2) + CO2 = (CO3- bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar20.1 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar92.0J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(CO3- bullet 5Carbon dioxide) + Carbon dioxide = (CO3- bullet 6Carbon dioxide)

By formula: (CO3- bullet 5CO2) + CO2 = (CO3- bullet 6CO2)

Quantity Value Units Method Reference Comment
Deltar19.5 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(CO2+ bullet 3Carbon dioxide) + Carbon dioxide = (CO2+ bullet 4Carbon dioxide)

By formula: (CO2+ bullet 3CO2) + CO2 = (CO2+ bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar20. ± 1.kJ/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(CO2+ bullet 4Carbon dioxide) + Carbon dioxide = (CO2+ bullet 5Carbon dioxide)

By formula: (CO2+ bullet 4CO2) + CO2 = (CO2+ bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar18. ± 1.kJ/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(Oxygen cation bullet 2Carbon dioxide) + Carbon dioxide = (Oxygen cation bullet 3Carbon dioxide)

By formula: (O2+ bullet 2CO2) + CO2 = (O2+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar26. ± 1.kJ/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.8J/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(Oxygen cation bullet 3Carbon dioxide) + Carbon dioxide = (Oxygen cation bullet 4Carbon dioxide)

By formula: (O2+ bullet 3CO2) + CO2 = (O2+ bullet 4CO2)

Quantity Value Units Method Reference Comment
Deltar21. ± 1.kJ/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(Oxygen cation bullet 4Carbon dioxide) + Carbon dioxide = (Oxygen cation bullet 5Carbon dioxide)

By formula: (O2+ bullet 4CO2) + CO2 = (O2+ bullet 5CO2)

Quantity Value Units Method Reference Comment
Deltar19. ± 2.kJ/molPHPMSHiraoka, Nakajima, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSHiraoka, Nakajima, et al., 1988gas phase; M

(CO3- bullet Carbon dioxide) + Carbon dioxide = (CO3- bullet 2Carbon dioxide)

By formula: (CO3- bullet CO2) + CO2 = (CO3- bullet 2CO2)

Quantity Value Units Method Reference Comment
Deltar24.0 ± 0.8kJ/molPHPMSHiraoka and Yamabe, 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka and Yamabe, 1992gas phase; M

(Hydronium cation bullet 2Carbon dioxide) + Carbon dioxide = (Hydronium cation bullet 3Carbon dioxide)

By formula: (H3O+ bullet 2CO2) + CO2 = (H3O+ bullet 3CO2)

Quantity Value Units Method Reference Comment
Deltar43.9kJ/molPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1992
Hiraoka, K.; Yamabe, S., Formation of the Chelate Bonds in the Cluster O2(-)(CO2)n, CO3(-)(CO2)n, and NO2(-)(CO2)n, J. Chem. Phys., 1992, 97, 1, 643, https://doi.org/10.1063/1.463560 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Peterson, Mark, et al., 1984
Peterson, K.I.; Mark, T.D.; Keesee, R.G.; Castleman, A.W., Thermochemical Properties of Gas - Phase Mixed Clusters: H2O/CO2 with Na+, J. Phys. Chem., 1984, 88, 13, 2880, https://doi.org/10.1021/j150657a042 . [all data]

Keller and Beyer, 1971
Keller, G.E.; Beyer, R.A., CO2 and O2 Clustering to Sodium Ions, J. Geophys. Res., 1971, 74, 1, 289, https://doi.org/10.1029/JA076i001p00289 . [all data]

Larson, Szulejko, et al., 1988
Larson, J.W.; Szulejko, J.E.; McMahon, T.B., Gas Phase Lewis Acid-Base Interactions. An Experimental Determination of Cyanide Binding Energies From Ion Cyclotron Resonance and High-Pressure Mass Spectrometric Equilibrium Measurements., J. Am. Chem. Soc., 1988, 110, 23, 7604, https://doi.org/10.1021/ja00231a004 . [all data]

Hiraoka and Yamabe, 1991
Hiraoka, K.; Yamabe, S., Cluster Ions: Gas Phase Stabilities of NO+(O2)n and NO+(CO2)n with n = 1 - 5, J. Chem. Phys., 1991, 95, 9, 6800, https://doi.org/10.1063/1.461518 . [all data]

Hiraoka, Mizuse, et al., 1987
Hiraoka, K.; Mizuse, S.; Yamabe, S., Stability and Structure of Cluster Ions: Halide Ions with CO2, J. Chem. Phys., 1987, 87, 6, 3647, https://doi.org/10.1063/1.452962 . [all data]

Hiraoka, Shoda, et al., 1986
Hiraoka, K.; Shoda, T.; Morise, K.; Yamabe, S.; Kawai, E.; Hirao, K., Stability and structure of cluster ions in the gas phase: Carbon dioxide with Cl-, H3O+, HCO2+ and HCO+, J. Chem. Phys., 1986, 84, 2091. [all data]

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Notes

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