Decane
- Formula: C10H22
- Molecular weight: 142.2817
- IUPAC Standard InChIKey: DIOQZVSQGTUSAI-UHFFFAOYSA-N
- CAS Registry Number: 124-18-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: n-Decane; n-C10H22; UN 2247
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Condensed phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -301.0 ± 1.1 | kJ/mol | Ccb | Prosen and Rossini, 1945 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -6778.33 ± 0.88 | kJ/mol | Ccb | Prosen and Rossini, 1945 | Corresponding ΔfHºliquid = -300.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°liquid | -6778.6 ± 1.5 | kJ/mol | Ccb | Prosen and Rossini, 1944 | Corresponding ΔfHºliquid = -300.6 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
ΔcH°liquid | -6774.2 | kJ/mol | Ccb | Jessup, 1937 | Corresponding ΔfHºliquid = -305.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 425.89 | J/mol*K | N/A | Finke, Gross, et al., 1954 | DH |
S°liquid | 428.9 | J/mol*K | N/A | Huffman, Parks, et al., 1931 | Extrapolation below 90 K, 92.05 J/mol*K.; DH |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
314.45 | 298.9 | Czarnota, 1993 | p = 0.1 MPa.; DH |
323.87 | 318.15 | Banipal, Garg, et al., 1991 | T = 313 to 373 K. p = 0.1 MPa.; DH |
315.46 | 298.15 | Trejo, Costas, et al., 1991 | DH |
315.46 | 298.15 | Andreoli-Ball, Patterson, et al., 1988 | DH |
315.32 | 298.15 | Costas, Huu, et al., 1988 | DH |
315.0 | 298.23 | Kuznetsov, Kharin, et al., 1988 | T = 293 to 420 K. p = 0.1 MPa. Unsmoothed experimental datum given as 2.214 kJ/kg*K.; DH |
313.46 | 298.15 | Perez-Casas, Aicart, et al., 1988 | DH |
313.13 | 298.15 | Pintos, Bravo, et al., 1988 | DH |
315.46 | 298.15 | Wilhelm, Inglese, et al., 1987 | DH |
313.56 | 298.15 | Gates, Wood, et al., 1986 | T = 298.15 to 368.15 K.; DH |
315.46 | 298.15 | Tardajos, Aicart, et al., 1986 | DH |
313.24 | 298.15 | Baluja, Bravo, et al., 1985 | DH |
314.82 | 298.15 | Costas and Patterson, 1985 | T = 283.15, 298.15, 313.15 K.; DH |
312.99 | 298.15 | Lainez, Rodrigo, et al., 1985 | DH |
313.09 | 298.15 | Lainez, Roux-Desgranges, et al., 1985 | DH |
313.09 | 298.15 | Lainez, Wilhelm, et al., 1985 | DH |
313.93 | 298.15 | Grolier, Inglese, et al., 1984 | DH |
314.21 | 298.15 | Roux, Grolier, et al., 1984 | DH |
310.26 | 293.15 | Siddiqi, Svejda, et al., 1983 | DH |
312.5 | 298.15 | Wilhelm, Inglese, et al., 1982 | DH |
312.8 | 298. | Zaripov, 1982 | T = 298, 323, 363 K.; DH |
313.3 | 298.15 | Grolier, Hamedi, et al., 1979 | DH |
311.7 | 298. | Grigor'ev, Rastorguev, et al., 1975 | T = 300 to 463 K.; DH |
314.47 | 298.15 | Finke, Gross, et al., 1954 | T = 12 to 300 K.; DH |
312.29 | 299.8 | Schlinger and Sage, 1952 | T = 80 to 200°F.; DH |
313.97 | 298.15 | Osborne and Ginnings, 1947 | T = 278 to 318 K.; DH |
311.3 | 297.7 | Huffman, Parks, et al., 1931 | T = 91 to 298 K. Value is unsmoothed experimental datum.; DH |
309.6 | 295.5 | Parks, Huffman, et al., 1930 | T = 242 to 296 K. Value is unsmoothed experimental datum.; DH |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 447.2 ± 0.3 | K | AVG | N/A | Average of 34 out of 43 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 243.3 ± 0.6 | K | AVG | N/A | Average of 23 out of 25 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 243.4 ± 0.3 | K | AVG | N/A | Average of 9 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 617.8 ± 0.7 | K | AVG | N/A | Average of 16 out of 18 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 21.1 ± 0.8 | bar | AVG | N/A | Average of 11 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Vc | 0.624 | l/mol | N/A | Ambrose and Tsonopoulos, 1995 | |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 1.60 ± 0.05 | mol/l | N/A | Ambrose and Tsonopoulos, 1995 | |
ρc | 1.67 | mol/l | N/A | Steele, 1992 | Uncertainty assigned by TRC = 0.070 mol/l; TRC |
ρc | 1.60 | mol/l | N/A | Anselme, Gude, et al., 1990 | Uncertainty assigned by TRC = 0.04 mol/l; TRC |
ρc | 1.67 | mol/l | N/A | Knipmeyer, Archer, et al., 1989 | Uncertainty assigned by TRC = 0.070 mol/l; TRC |
ρc | 1.595 | mol/l | N/A | Gehrig and Lentz, 1983 | Uncertainty assigned by TRC = 0.04 mol/l; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 51.3 ± 0.3 | kJ/mol | AVG | N/A | Average of 12 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 80.3 | kJ/mol | B | Swain, Kwan, et al., 1980 | AC |
ΔsubH° | 82.4 | kJ/mol | H | Bondi, 1963 | See also Chickos, Hosseini, et al., 1993.; AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
38.75 | 447.3 | N/A | Majer and Svoboda, 1985 | |
48.3 | 339. | GC | Mokbel, Razzouk, et al., 2007 | Based on data from 324. to 402. K.; AC |
46.6 | 352. | N/A | Batiu, 2002 | Based on data from 337. to 376. K.; AC |
51.5 | 299. | C | Viton, Chavret, et al., 1996 | AC |
50.5 | 314. | C | Viton, Chavret, et al., 1996 | AC |
50.1 | 324. | C | Viton, Chavret, et al., 1996 | AC |
49.2 | 334. | C | Viton, Chavret, et al., 1996 | AC |
42.5 | 424. | N/A | Lee, Dempsey, et al., 1992 | Based on data from 409. to 584. K.; AC |
48.1 | 340. | EB,IP | Chirico, Nguyen, et al., 1989 | Based on data from 268. to 490. K.; AC |
53.8 | 267. | A | Stephenson and Malanowski, 1987 | Based on data from 252. to 383. K.; AC |
41.7 | 462. | A | Stephenson and Malanowski, 1987 | Based on data from 447. to 526. K.; AC |
38.6 | 539. | A | Stephenson and Malanowski, 1987 | Based on data from 524. to 617. K.; AC |
45.3 | 388. | N/A | Stephenson and Malanowski, 1987 | Based on data from 373. to 443. K. See also Varushchenko, Belikova, et al., 1970.; AC |
50.3 | 313. | GS | Allemand, Jose, et al., 1986 | Based on data from 298. to 347. K.; AC |
49.8 ± 1.7 | 308. to 351. | N/A | Beckhaus, Ruchardt, et al., 1984 | AC |
55.9 | 258. | N/A | Carruth and Kobayashi, 1973 | Based on data from 243. to 310. K.; AC |
45.5 | 383. | MM | Willingham, Taylor, et al., 1945 | Based on data from 368. to 440. K.; AC |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kJ/mol)
Tr = reduced temperature (T / Tc)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A (kJ/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
298. to 444. | 74.38 | 0.3238 | 617.4 | Majer and Svoboda, 1985 |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
243.49 to 310.59 | 0.21021 | 440.616 | -156.896 | Carruth and Kobayashi, 1973 | Coefficents calculated by NIST from author's data. |
367.63 to 448.27 | 4.07857 | 1501.268 | -78.67 | Williamham, Taylor, et al., 1945 |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
84.8 | 243. | B | Bondi, 1963 | AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
28.715 | 243.51 | N/A | Finke, Gross, et al., 1954 | DH |
27.6 | 243. | DSC | Marti, Kaisersberger, et al., 2004 | AC |
28.7 | 243.5 | N/A | Domalski and Hearing, 1996 | AC |
28.778 | 243.1 | N/A | Huffman, Parks, et al., 1931 | DH |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
117.92 | 243.51 | Finke, Gross, et al., 1954 | DH |
117.99 | 243.5 | Domalski and Hearing, 1996 | CAL |
118.4 | 243.1 | Huffman, Parks, et al., 1931 | DH |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Prosen and Rossini, 1945
Prosen, E.J.; Rossini, F.D.,
Heats of combustion and formation of the paraffin hydrocarbons at 25° C,
J. Res. NBS, 1945, 263-267. [all data]
Prosen and Rossini, 1944
Prosen, E.J.; Rossini, F.D.,
Heats of combustion of eight normal paraffin hydrocarbons in the liquid state,
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Jessup, 1937
Jessup, R.S.,
Heats of combustion of the liquid normal paraffin hydrocarbons from hexane to dodecane,
J. Res. NBS, 1937, 18, 114-128. [all data]
Finke, Gross, et al., 1954
Finke, H.L.; Gross, M.E.; Waddington, G.; Huffman, H.M.,
Low-temperature thermal data for the nine normal paraffin hydrocarbons from octane to hexadecane,
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Huffman, Parks, et al., 1931
Huffman, H.M.; Parks, G.S.; Barmore, M.,
Thermal data on organic compounds. X. Further studies on the heat capacities, entropies and free energies of hydrocarbons,
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Czarnota, I.,
Heat capacity of decane at high pressures,
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Banipal, Garg, et al., 1991
Banipal, T.S.; Garg, S.K.; Ahluwalia, J.C.,
Heat capacities and densities of liquid n-octane, n-nonane, n-decane, and n-hexadecane at temperatures from 318.15 to 373.15 K and at pressures up to 10 MPa,
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Trejo, Costas, et al., 1991
Trejo, L.M.; Costas, M.; Patterson, D.,
Excess heat capacity of organic mixtures, Internat. DATA Series,
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Heat capacity and corresponding states in alkan-1-ol-n-alkane systems, J. Chem. Soc.,
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Liquid structure and second-order mixing functions for l-chloronaphthalene with linear and branched alkanes, J. Chem. Soc.,
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Isobaric heat capacity of n-alkanes C7 to C10 at temperatures 293 to 630 K and pressures up to 60 MPa, Izv. Vyssh. Ucheb. Zabed.,
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Perez-Casas, S.; Aicart, E.; Trojo, L.M.; Costas, M.,
Excess heat capacity. Chlorobenzene-2,2,4,4,6,8,8-heptamethylnonane, Int. Data Ser.,
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Excess enthalpy, excess heat capacity and excess volume of 1,2,4-trimethylbenzene +, and 1-methylnaphthalene + an n-alkane,
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Densities and heat capacities of 1-butanol + n-decane from 298 K to 400 K,
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Baluja, M.C.; Bravo, R.; Pintos, M.; Paz Andrade, M.I.; Roux-Desgranges, G.; Grolier, J.-P.E.,
Unusual dependence on concentration of the excess heat capacities of ester solutions in alkanes,
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Costas and Patterson, 1985
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Self-association of alcohols in inert solvents, J. Chem. Soc.,
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Relations between structure and thermodynamic properties. Heat capacities of polar substances (nitrobenzene and benzonitrile) in alkane solutions,
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Lainez, A.; Wilhelm, E.; Roux-Desgranges, G.; Grolier, J.-P.E.,
Excess molar quantities of (a halogenated n-alkane + an n-alkane). A comparative study of mixtures containing either 1-chlorobutane or 1,4-dichlorobutane,
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Excess molar heat capacities of (1,4-dioxane + an n-alkane): an unusual composition dependence,
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Excess molar enthalpies, excess molar heat capacities and excess molar volumes of (fluorobenzene + an n-alkane),
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A generalized van der Waals equation of state II. Excess heat capacities of mixtures containing cycloalkanes (C5,C6), methylcycloalkanes (C5,C6) and n-decane,
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Wilhelm, E.; Inglese, A.; Quint, J.R.; Grolier, J.-P.E.,
Molar excess volumes and excess heat capacities of (1,2,4-trichlorobenzene + an alkane),
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Zaripov, 1982
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Experimental study of the isobaric heat capacity of liquid organic compounds with molecular weights of up to 4000 a.e.m., 1982, Teplomassoobmen Teplofiz. [all data]
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Excess heat capacities of binary mixtures of carbon tetrachloride with n-alkanes at 298.15 K,
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Experimental determination of the isobaric specific heat of n-alkanes,
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Schlinger, W.G.; Sage, B.H.,
Isobaric heat capacities at bubble point. cis-2-butene, isopropylbenzene, and n-decane,
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Osborne and Ginnings, 1947
Osborne, N.S.; Ginnings, D.C.,
Measurements of heat of vaporization and heat capacity of a number of hydrocarbons,
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Parks, Huffman, et al., 1930
Parks, G.S.; Huffman, H.M.; Thomas, S.B.,
Thermal data on organic compounds. VI. The heat capacities, entropies and free energies of some saturated, non-benzenoid hydrocarbons,
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The Critical Temperatures and Densities of the n-Alkanes from Pentane to Octadecane,
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High-temperature enthalpy and critical property measurements using differential scanning calorimeter,
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Values of the pressure-molar volume-temperature relationship for n-decane up to 300 MPa and 673 K,
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Swain, H.A.; Kwan, Chiu-Yin; Sung, Ho-Nan,
Measurement of vapor pressures from 20 to 30.degree.C of long-chain peroxy acids,
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Bondi, A.,
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Heat capacity corrections to a standard state: a comparison of new and some literature methods for organic liquids and solids,
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A Gas Saturation Apparatus for Very Low Vapor or Sublimation Pressure Measurements (10 -3 Pa): Vapor-Liquid Equilibria of n -Alkanes ( n -C 10 , n -C 24 , n -C 28 ),
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Batiu, I.,
Vapor--liquid equilibria in the binary systems n-decane+(-)-menthone and n-decane+(+)-fenchone at temperatures between 344.45 and 390.75 K,
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Enthalpies of vaporization of normal alkanes from nonane to pentadecane at temperatures from 298 to 359 K,
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Lee, Chang Ha; Dempsey, Dennis M.; Mohamed, Rahoma S.; Holder, Gerald D.,
Vapor-liquid equilibria in the systems of n-decane/tetralin, n-hexadecane/tetralin, n-decane/1-methylnaphthalene, and 1-methylnaphthalene/tetralin,
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Vapor pressure of n-alkanes revisited. New high-precision vapor pressure data on n-decane, n-eicosane, and n-octacosane,
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Allemand, Jose, et al., 1986
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Mesure des pressions de vapeur d'hydrocarbures C10 A C18n-alcanes etn-alkylbenzenes dans le domaine 3-1000 pascal,
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Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Pc Critical pressure S°liquid Entropy of liquid at standard conditions Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature Vc Critical volume ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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