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Butanal

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-245.4 ± 0.84kJ/molCmWiberg, Crocker, et al., 1991ALS
Deltafliquid-238.1 ± 1.5kJ/molChydBuckley and Cox, 1967ALS
Deltafliquid-240.3kJ/molCcbNicholson, 1960ALS
Deltafliquid-238.7 ± 0.71kJ/molCcbTjebbes, 1960ALS
Quantity Value Units Method Reference Comment
Deltacliquid-2477.1 ± 1.4kJ/molCcbNicholson, 1960Corresponding «DELTA»fliquid = -240.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2478.7 ± 0.71kJ/molCcbTjebbes, 1960Corresponding «DELTA»fliquid = -238.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid242.7J/mol*KN/AVasil'ev and Lebedev, 1989DH
liquid246.9J/mol*KN/AParks, Kennedy, et al., 1956Extrapolation below 80 K, 43.93 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
164.7298.15Vasil'ev and Lebedev, 1989T = 11 to 330 K.; DH
163.51298.15Parks, Kennedy, et al., 1956T = 80 to 300 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg, Crocker, et al., 1991
Wiberg, K.B.; Crocker, L.S.; Morgan, K.M., Thermochemical studies of carbonyl compounds. 5. Enthalpies of reduction of carbonyl groups, J. Am. Chem. Soc., 1991, 113, 3447-3450. [all data]

Buckley and Cox, 1967
Buckley, E.; Cox, J.D., Chemical equilibria. Part 2.-Dehydrogenation of propanol and butanol, Trans. Faraday Soc., 1967, 63, 895-901. [all data]

Nicholson, 1960
Nicholson, G.R., 478. The heats of combustion of butanal and heptanal, J. Chem. Soc., 1960, 2377-2378. [all data]

Tjebbes, 1960
Tjebbes, J., Heats of combustion of butannal and some related compounds, Acta Chem. Scand., 1960, 14, 180-188. [all data]

Vasil'ev and Lebedev, 1989
Vasil'ev, V.G.; Lebedev, B.V., Thermodynamics of butanal in the temperature range 0-330K, Zh. Obshch. Khim., 1989, 59(11), 2415-2420. [all data]

Parks, Kennedy, et al., 1956
Parks, G.S.; Kennedy, W.D.; Gates, R.R.; Mosley, J.R.; Moore, G.E.; Renquist, M.L., Thermal data on organic compounds. XXVI. Some heat capacity, entropy and free energy data for seven compounds containing oxygen., Not In System, 1956, 78, 56-59. [all data]


Notes

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