4-Heptanone
- Formula: C7H14O
- Molecular weight: 114.1855
- IUPAC Standard InChI: InChI=1S/C7H14O/c1-3-5-7(8)6-4-2/h3-6H2,1-2H3
- IUPAC Standard InChIKey: HCFAJYNVAYBARA-UHFFFAOYSA-N
- CAS Registry Number: 123-19-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Butyrone; Dipropyl ketone; GBL; Propyl ketone; (n-C3H7)2CO; Heptan-4-one; Di-n-propyl ketone; UN 2710; NSC 8692
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Normal boiling point
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
| Tboil (K) | Reference | Comment |
|---|---|---|
| 417.2 | Weast and Grasselli, 1989 | BS |
| 415.65 | Smith, 1960 | Uncertainty assigned by TRC = 3. K; TRC |
| 414.65 | Ishiguro, Morita, et al., 1957 | Uncertainty assigned by TRC = 5. K; TRC |
| 416.65 | Widom, Philippe, et al., 1957 | Uncertainty assigned by TRC = 1. K; TRC |
| 416.15 | Fitzpatrick and Gettler, 1956 | Uncertainty assigned by TRC = 2. K; TRC |
| 415.4 | Shuikin and Bel'skii, 1956 | Uncertainty assigned by TRC = 1.5 K; TRC |
| 416.15 | Kornblum, Smiley, et al., 1955 | Uncertainty assigned by TRC = 3. K; TRC |
| 417.15 | Cook, 1952 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 418.4 | Bridson-Jones and Buckley, 1951 | Uncertainty assigned by TRC = 1. K; TRC |
| 417.65 | Man and Hauser, 1950 | Uncertainty assigned by TRC = 1. K; TRC |
| 416.7 | Lecat, 1949 | Uncertainty assigned by TRC = 1. K; TRC |
| 416.70 | Lecat, 1947 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 417.15 | Coley and Komarewsky, 1946 | Uncertainty assigned by TRC = 1. K; TRC |
| 419.15 | Ipatieff and Haensel, 1942 | Uncertainty assigned by TRC = 2. K; TRC |
| 417.2 | Saylor, Baxt, et al., 1942 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 416.65 | Reeve and Adkins, 1940 | Uncertainty assigned by TRC = 2. K; TRC |
| 424.65 | Schaad and Ipatieff, 1940 | Uncertainty assigned by TRC = 5. K; TRC; Data excluded from overall average |
| 419.15 | Stutsman and Adkins, 1939 | Uncertainty assigned by TRC = 2. K; TRC |
| 417.23 | Rintelen, Saylor, et al., 1937 | Uncertainty assigned by TRC = 0.2 K; TRC |
| 416.05 | Kohlraush and Koppl, 1934 | Uncertainty assigned by TRC = 2. K; TRC |
| 414.15 | Ziegler, Eberle, et al., 1933 | Uncertainty assigned by TRC = 3. K; TRC |
| 415.65 | Grignard and Fluchaire, 1928 | Uncertainty assigned by TRC = 2. K; TRC |
| 417.4 | Timmermans, 1927 | Uncertainty assigned by TRC = 0.5 K; source of data not clear; TRC |
| 417.25 | Timmermans, 1921 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 417.15 | Mailhe, 1909 | Uncertainty assigned by TRC = 1. K; TRC |
| 418.15 | Senderens, 1909 | Uncertainty assigned by TRC = 1. K; TRC |
| 416.67 | Louguinine, 1898 | Uncertainty assigned by TRC = 0.2 K; TRC |
| 416.65 | Bruhl, 1894 | Uncertainty assigned by TRC = 0.5 K; TRC |
| 416.65 | Berthelot, 1881 | Uncertainty assigned by TRC = 1. K; TRC |
| 413.15 | Lieben and Volker, 1875 | Uncertainty assigned by TRC = 5. K; TRC |
| 413.15 | Lieben, 1875 | Uncertainty assigned by TRC = 5. K; TRC |
References
Go To: Top, Normal boiling point, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Smith, 1960
Smith, R.F.,
J. Org. Chem., 1960, 25, 453-54. [all data]
Ishiguro, Morita, et al., 1957
Ishiguro; Morita; Ikushima,
Yakugaku Zasshi, 1957, 77, 660. [all data]
Widom, Philippe, et al., 1957
Widom, J.M.; Philippe, R.J.; Hobbs, M.E.,
J. Am. Chem. Soc., 1957, 79, 1383. [all data]
Fitzpatrick and Gettler, 1956
Fitzpatrick, F.W.; Gettler, J.D.,
J. Am. Chem. Soc., 1956, 78, 530. [all data]
Shuikin and Bel'skii, 1956
Shuikin, N.I.; Bel'skii, I.F.,
Hydrogenation and Hydrogenolysis of alpha-Ethyl and alpha-Propenyl- furan on Raney Nickel Catalyst,
J. Gen. Chem. USSR (Engl. Transl.), 1956, 26, 3025. [all data]
Kornblum, Smiley, et al., 1955
Kornblum, N.; Smiley, R.A.; Ungnade, H.E.; White, A.M.; Taub, B.,
The reaction of silver nitrite with secondary and tertiary alkyl halides,
J. Am. Chem. Soc., 1955, 77, 5528-33. [all data]
Cook, 1952
Cook, N.C.,
, Unpublished, Final Rep. Stand. Proj. on Oxygenated Compounds, Penn. State Univ., College Park, PA, 1952. [all data]
Bridson-Jones and Buckley, 1951
Bridson-Jones, F.S.; Buckley, G.D.,
Oxidation of organic compounds by nitrous oxide: II tri- and tetra- substituted ethylenes,
J. Chem. Soc., 1951, 1951, 3009. [all data]
Man and Hauser, 1950
Man, E.H.; Hauser, C.R.,
J. Am. Chem. Soc., 1950, 72, 3294. [all data]
Lecat, 1949
Lecat, M.,
Tables Azeotropiques, Vol. 1, 10th ed., Brussels, Belgium, 1949. [all data]
Lecat, 1947
Lecat, M.,
Orthobaric Azeotropes of Sulfides,
Bull. Cl. Sci., Acad. R. Belg., 1947, 33, 160-82. [all data]
Coley and Komarewsky, 1946
Coley, J.R.; Komarewsky, V.I.,
Catalytic conversion of aldols over chromia catalysts,
J. Am. Chem. Soc., 1946, 68, 716. [all data]
Ipatieff and Haensel, 1942
Ipatieff, V.N.; Haensel, V.,
J. Org. Chem., 1942, 7, 189. [all data]
Saylor, Baxt, et al., 1942
Saylor, J.H.; Baxt, V.J.; Gross, P.M.,
Solubility studies: vii the solubilities of some isomeric ketones in water,
J. Am. Chem. Soc., 1942, 64, 2742-4. [all data]
Reeve and Adkins, 1940
Reeve, E.W.; Adkins, H.,
J. Am. Chem. Soc., 1940, 62, 2874. [all data]
Schaad and Ipatieff, 1940
Schaad, R.E.; Ipatieff, V.N.,
Catalytic Hydration of Acetylene and Some Alkylacetylenes,
J. Am. Chem. Soc., 1940, 62, 178. [all data]
Stutsman and Adkins, 1939
Stutsman, P.S.; Adkins, H.,
Hydrogenation of 1,3-Diketones to Ketols,
J. Am. Chem. Soc., 1939, 61, 3303-6. [all data]
Rintelen, Saylor, et al., 1937
Rintelen, J.C.; Saylor, J.H.; Gross, P.M.,
The Densities and Vapor Pressures of Some Alkylbenzene, Aliphatic Ketones and n-AMyl Chloride,
J. Am. Chem. Soc., 1937, 59, 1129. [all data]
Kohlraush and Koppl, 1934
Kohlraush, K.W.F.; Koppl, F.,
Z. Phys. Chem., Abt. B, 1934, 24, 370. [all data]
Ziegler, Eberle, et al., 1933
Ziegler; Eberle; Ohlinger,
Justus Liebigs Ann. Chem., 1933, 504, 94. [all data]
Grignard and Fluchaire, 1928
Grignard, V.; Fluchaire, M.,
Suiz les proprietetes condensantes des alcoolates magnesiens mixtures,
Ann. Chim. (Paris), 1928, 9, 5. [all data]
Timmermans, 1927
Timmermans, J.,
The Melting Point of Organic Substances,
Bull. Soc. Chim. Belg., 1927, 36, 502. [all data]
Timmermans, 1921
Timmermans, J.,
The Freezing Points of Organic Substances IV. New Exp. Determinations,
Bull. Soc. Chim. Belg., 1921, 30, 62. [all data]
Mailhe, 1909
Mailhe, A.,
Bull. Soc. Chim. Fr., 1909, 5, 616. [all data]
Senderens, 1909
Senderens, J.B.,
C. R. Hebd. Seances Acad. Sci., 1909, 148, 927. [all data]
Louguinine, 1898
Louguinine, W.,
Study of Latent Heats of Vaporizaion of Some Liquids,
Ann. Chim. Phys., 1898, 13, 289-377. [all data]
Bruhl, 1894
Bruhl, J.W.,
Studies on tautomery,
J. Prakt. Chem., 1894, 50, 119. [all data]
Berthelot, 1881
Berthelot, M.,
Ann. Chim. Phys., 1881, 23, 176. [all data]
Lieben and Volker, 1875
Lieben, A.; Volker, O.,
Chem. Ber., 1875, 8, 1019. [all data]
Lieben, 1875
Lieben, A.,
Mitheilungen aus dem universitatslaboatorium zu wein,
Chem. Ber., 1875, 8, 1017. [all data]
Notes
Go To: Top, Normal boiling point, References
- Symbols used in this document:
Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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