Benzaldehyde, 4-methoxy-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-247.kJ/molCcbZavoianu, Contineanu, et al., 1986 
Quantity Value Units Method Reference Comment
Δcliquid-4047.kJ/molCcbZavoianu, Contineanu, et al., 1986Corresponding Δfliquid = -244. kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-4024.2 ± 7.5kJ/molCcbManzoni-Ansidei and Storto, 1940Reanalyzed by Cox and Pilcher, 1970, Original value = -4028.9 kJ/mol; Corresponding Δfliquid = -267.2 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil521.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil521.KN/AAmerican Tokyo Kasei, 1988BS
Tboil521.15KN/AGrimm and Patrick, 1923Uncertainty assigned by TRC = 0.5 K; TRC
Tboil520.15KN/AAtkins, 1915Uncertainty assigned by TRC = 3. K; TRC
Tboil521.15KN/APerkin, 1896Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Tfus273.12KN/APerkin, 1896Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Δvap60.4kJ/molAStephenson and Malanowski, 1987Based on data from 283. to 323. K. See also Serpinskii, Voitkevich, et al., 1955.; AC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
57.1361.AStephenson and Malanowski, 1987Based on data from 346. to 521. K. See also Stull, 1947.; AC
58.4363.A,EBScholz and Brunner, 1985Based on data from 348. to 521. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zavoianu, Contineanu, et al., 1986
Zavoianu, D.; Contineanu, I.; Moga-Gheorghe, S.; Marchidan, D., Structure and reactivity of nitriles. Condensation reaction of phenylacetonitrile with benzaldehydes, Rev. Chim. (Bucharest), 1986, 37, 1055-1058. [all data]

Manzoni-Ansidei and Storto, 1940
Manzoni-Ansidei, R.; Storto, T., Experimentelle beitrage zum problem der chelatringbildung. IX. Thermochemische untersuchungen an einigen methoxybenzaldehyden, Atti. R. Acad. Italia. Rend. Classe Sci. Fis. Mat. Nat., 1940, 1, 465. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

American Tokyo Kasei, 1988
American Tokyo Kasei, TCI American Organic Chemical 88/89 Catalog, American Tokyo Kasei, Portland, OR, 1988, 1610. [all data]

Grimm and Patrick, 1923
Grimm, F.V.; Patrick, W.A., The Dielectric Constastants of Organic Liquids at the Boilin Point, J. Am. Chem. Soc., 1923, 45, 2794. [all data]

Atkins, 1915
Atkins, W.R.G., Spectrochemical Experiments, Justus Liebigs Ann. Chem., 1915, 408, 212. [all data]

Perkin, 1896
Perkin, W.H., LXIX. On Magnetic Rotatory Power, especially of Aromatic Compounds, J. Chem. Soc., 1896, 69, 1025-1257. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Serpinskii, Voitkevich, et al., 1955
Serpinskii, V.V.; Voitkevich, S.A.; Lyuboshits, N. Yu, Zh. Fiz. Khim., 1955, 29, 653. [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Scholz and Brunner, 1985
Scholz, Andreas G.R.; Brunner, Erwin, Isobaric vapor-liquid equilibria of the binary systems consisting of anisaldehyde, methyl anisate, and anisyl alcohol at 2 kPa, J. Chem. Eng. Data, 1985, 30, 1, 72-74, https://doi.org/10.1021/je00039a024 . [all data]


Notes

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