1,4-Bis(2-hydroxyethyl)piperazine
- Formula: C8H18N2O2
- Molecular weight: 174.2407
- IUPAC Standard InChIKey: VARKIGWTYBUWNT-UHFFFAOYSA-N
- CAS Registry Number: 122-96-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: N,N'-Bis(2-hydroxyethyl)piperazine; di(N-Hydroxyethyl)piperazine; 1,4-Piperazinediethanol; N,N'-Bis(β-hydroxyethyl)piperazine; N,N'-Di(2-hydroxyethyl)piperazine; N,N'-Dihydroxyethylpiperazine; Piperazine, N,N'-bis(2-hydroxyethyl)-; 1,4-Bis(β-hydroxyethyl)piperazine; 1,4-Di(2-hydroxyethyl)piperazine; NSC 26892; NSC 36645; piperazine-1,4-diethanol
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 551. | K | N/A | Lebedeva, Gutner, et al., 1984 | DH |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 405. | K | N/A | Lebedeva, Gutner, et al., 1984, 2 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 130.5 ± 1.0 | kJ/mol | GS | Verevkin, 2002 | Based on data from 354. to 396. K.; AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
67.8 ± 5.3 | 413. to 507. | Abdi and Meisen, 1998 | AC |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
128.0 ± 1.0 | 375. | GS | Verevkin, 2002 | Based on data from 354. to 396. K.; AC |
104.1 ± 4.6 | 334. | V | Lebedeva, Gutner, et al., 1984, 3 | ALS |
104.1 | 334. to 356. | N/A | Lebedeva, Gutner, et al., 1984, 2 | AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
25.900 | 405. | Lebedeva, Gutner, et al., 1984 | DH |
25.9 | 405. | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
64.0 | 405. | Lebedeva, Gutner, et al., 1984 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lebedeva, Gutner, et al., 1984
Lebedeva, N.D.; Gutner, N.M.; Katin, Yu.A.; Kozlova, N.M.; Kiseleva, N.N.; Machinya, E.F.; Dobychin, S.L.; Thermochemical study of bis(hydroxyethyl)piperazine, N.,
N-dimethylpropylenediamine and 2,2-azodiisobutyric acid dinitrile,
Zhur. Prikl. Khim. (Leningrad), 1984, 57(10), 2297-2301. [all data]
Lebedeva, Gutner, et al., 1984, 2
Lebedeva, N.D.; Gutner, N.M.; Katin, Y.A.; Kozlova, N.M.; Kiseleva, N.N.; Makhina, E.F.; Dobychin, S.K.,
Zh. Prikl. Khim., 1984, 57, 2297. [all data]
Verevkin, 2002
Verevkin, Sergey P.,
Relationships among strain energies of mono- and poly-cyclic cyclohexanoid molecules and strain of their component rings,
The Journal of Chemical Thermodynamics, 2002, 34, 2, 263-275, https://doi.org/10.1006/jcht.2001.0896
. [all data]
Abdi and Meisen, 1998
Abdi, Majid Abedinzadegan; Meisen, Axel,
Vapor Pressure Measurements of Bis(hydroxyethyl)piperazine and Tris(hydroxyethyl)ethylenediamine,
J. Chem. Eng. Data, 1998, 43, 2, 133-137, https://doi.org/10.1021/je970146m
. [all data]
Lebedeva, Gutner, et al., 1984, 3
Lebedeva, N.D.; Gutner, N.M.; Katin, Yu.A.; Kozlova, N.M.; Kiseleva, N.N.; Makhina, E.F.; Dobychin, S.L.,
Thermochemical study of bis-hydroxyethylpiperazine, N,N-dimethylpropylenediamine, and 2,2-azodiisobutyrodinitrile,
J. Appl. Chem. USSR, 1984, 57, 2118-2122. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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