1,4-Bis(2-hydroxyethyl)piperazine
- Formula: C8H18N2O2
- Molecular weight: 174.2407
- IUPAC Standard InChIKey: VARKIGWTYBUWNT-UHFFFAOYSA-N
- CAS Registry Number: 122-96-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: N,N'-Bis(2-hydroxyethyl)piperazine; di(N-Hydroxyethyl)piperazine; 1,4-Piperazinediethanol; N,N'-Bis(β-hydroxyethyl)piperazine; N,N'-Di(2-hydroxyethyl)piperazine; N,N'-Dihydroxyethylpiperazine; Piperazine, N,N'-bis(2-hydroxyethyl)-; 1,4-Bis(β-hydroxyethyl)piperazine; 1,4-Di(2-hydroxyethyl)piperazine; NSC 26892; NSC 36645; piperazine-1,4-diethanol
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Phase change data
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 551. | K | N/A | Lebedeva, Gutner, et al., 1984 | DH |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 405. | K | N/A | Lebedeva, Gutner, et al., 1984, 2 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 31.19 ± 0.24 | kcal/mol | GS | Verevkin, 2002 | Based on data from 354. to 396. K.; AC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
16.2 ± 1.3 | 413. to 507. | Abdi and Meisen, 1998 | AC |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
30.59 ± 0.24 | 375. | GS | Verevkin, 2002 | Based on data from 354. to 396. K.; AC |
24.9 ± 1.1 | 334. | V | Lebedeva, Gutner, et al., 1984, 3 | ALS |
24.88 | 334. to 356. | N/A | Lebedeva, Gutner, et al., 1984, 2 | AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
6.1902 | 405. | Lebedeva, Gutner, et al., 1984 | DH |
6.19 | 405. | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
15.3 | 405. | Lebedeva, Gutner, et al., 1984 | DH |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-7665 |
NIST MS number | 235782 |
References
Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lebedeva, Gutner, et al., 1984
Lebedeva, N.D.; Gutner, N.M.; Katin, Yu.A.; Kozlova, N.M.; Kiseleva, N.N.; Machinya, E.F.; Dobychin, S.L.; Thermochemical study of bis(hydroxyethyl)piperazine, N.,
N-dimethylpropylenediamine and 2,2-azodiisobutyric acid dinitrile,
Zhur. Prikl. Khim. (Leningrad), 1984, 57(10), 2297-2301. [all data]
Lebedeva, Gutner, et al., 1984, 2
Lebedeva, N.D.; Gutner, N.M.; Katin, Y.A.; Kozlova, N.M.; Kiseleva, N.N.; Makhina, E.F.; Dobychin, S.K.,
Zh. Prikl. Khim., 1984, 57, 2297. [all data]
Verevkin, 2002
Verevkin, Sergey P.,
Relationships among strain energies of mono- and poly-cyclic cyclohexanoid molecules and strain of their component rings,
The Journal of Chemical Thermodynamics, 2002, 34, 2, 263-275, https://doi.org/10.1006/jcht.2001.0896
. [all data]
Abdi and Meisen, 1998
Abdi, Majid Abedinzadegan; Meisen, Axel,
Vapor Pressure Measurements of Bis(hydroxyethyl)piperazine and Tris(hydroxyethyl)ethylenediamine,
J. Chem. Eng. Data, 1998, 43, 2, 133-137, https://doi.org/10.1021/je970146m
. [all data]
Lebedeva, Gutner, et al., 1984, 3
Lebedeva, N.D.; Gutner, N.M.; Katin, Yu.A.; Kozlova, N.M.; Kiseleva, N.N.; Makhina, E.F.; Dobychin, S.L.,
Thermochemical study of bis-hydroxyethylpiperazine, N,N-dimethylpropylenediamine, and 2,2-azodiisobutyrodinitrile,
J. Appl. Chem. USSR, 1984, 57, 2118-2122. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Phase change data, Mass spectrum (electron ionization), References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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