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Ethyl orthoformate

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-675.8 ± 0.8kJ/molCcbGutner, Lebedeva, et al., 1980 
Deltafliquid-687.0kJ/molCmHine and Klueppet, 1974Heat of hydrolysis
Deltafliquid-681.3 ± 2.9kJ/molCcbPihlaja and Tuomi, 1971 
Quantity Value Units Method Reference Comment
Deltacliquid-4365.5 ± 0.8kJ/molCcbGutner, Lebedeva, et al., 1980Corresponding «DELTA»fliquid = -675.7 kJ/mol (simple calculation by NIST; no Washburn corrections)
Deltacliquid-4359.9 ± 2.9kJ/molCcbPihlaja and Tuomi, 1971Corresponding «DELTA»fliquid = -681.32 kJ/mol (simple calculation by NIST; no Washburn corrections)

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gutner, Lebedeva, et al., 1980
Gutner, N.M.; Lebedeva, N.D.; Dobychin, S.L.; Kiseleva, N.N., Thermochemical study of aliphatic ethers, J. Appl. Chem. USSR, 1980, 53, 1523-1525. [all data]

Hine and Klueppet, 1974
Hine, J.; Klueppet, A.W., Structural effects on rates and equilibria. XVIII. Thermodynamic stability of ortho esters, J. Am. Chem. Soc., 1974, 96, 2924-2929. [all data]

Pihlaja and Tuomi, 1971
Pihlaja, K.; Tuomi, M., Bond-bond interactions in organic oxygen compounds. Part V. Enthalpies of formation of methyl and ethyl orthoformates and the contributory group increments. The magnitude of the so-called rabbit-ear effect in acyclic oxygen compounds, Acta Chem. Scand., 1971, 25, 465-469. [all data]


Notes

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