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Diphenylamine

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid132.kJ/molCcbVriens and Hill, 1952 
Quantity Value Units Method Reference Comment
Deltacliquid-6426.2kJ/molCcbVriens and Hill, 1952 
Quantity Value Units Method Reference Comment
Deltafsolid130.0 ± 1.5kJ/molCcbMedard, 1955Reanalyzed by Cox and Pilcher, 1970, Original value = 140.6 ± 1.5 kJ/mol; Heat of combustion corrected for pressure
Deltafsolid142.5kJ/molCcbMedard, 1954crystal phase; Heat of combustion corrected for pressure
Deltafsolid117.4 ± 2.1kJ/molCmCole and Gilbert, 1951Reanalyzed by Cox and Pilcher, 1970, Original value = 116.9 kJ/mol
Deltafsolid131.kJ/molCcbSchmidt and Becker, 1933 
Deltafsolid109.kJ/molCcbLemoult, 1907 
Quantity Value Units Method Reference Comment
Deltacsolid-6424. ± 20.kJ/molAVGN/AAverage of 7 values; Individual data points

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vriens and Hill, 1952
Vriens, G.N.; Hill, A.G., Equilibria of several reactions of aromatic amines, Ind. Eng. Chem., 1952, 44, 2732-27. [all data]

Medard, 1955
Medard, L., La chaleur de combustion de la diphenylamine et l'energie de la liaison n - n, J. Chem. Phys., 1955, 52, 467-472. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Medard, 1954
Medard, L., Tables thermochimiques a l'usage des techniciens des substances explosives, Mem. Artillerie Fr. Sci. Tech. Armement, 1954, 28, 415-492. [all data]

Cole and Gilbert, 1951
Cole, L.G.; Gilbert, E.C., The heats of combustion of some nitrogen compounds and the apparent energy of the N-N bond, J. Am. Chem. Soc., 1951, 73, 5423-5427. [all data]

Schmidt and Becker, 1933
Schmidt, V.A.; Becker, F., Die Bildungswarme von Nitrocellulofen, Nitroglycerin und anderen widuigen Beltandteilen von Treibmitteln, Z. Gesamte Schiess Sprengstoffwes., 1933, 33, 280-282. [all data]

Lemoult, 1907
Lemoult, M.P., Recherches theoriques et experimentales sur les chaleurs de combustion et de formation des composes organiques, Ann. Chim. Phys., 1907, 12, 395-432. [all data]


Notes

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