S2 anion
- Formula: S2-
- Molecular weight: 64.131
- CAS Registry Number: 12185-15-8
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Protonation reactions
S2- + = HS2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 329.9 ± 3.7 | kcal/mol | D-EA | Moran and Ellison, 1988 | gas phase |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | >344.60 | kcal/mol | IMRB | Goodings, Bohme, et al., 1986 | gas phase; S- deprotonates H2S, Sn- for n≥2, does not. |
Ion clustering data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
S2- = CS4-
By formula: S2- = CS4-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.1 ± 1.5 | kcal/mol | TDAs | Hiraoka, Fujimaki, et al., 1994 | gas phase; B |
By formula: S2- + CS2 = (S2- • CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 19.1 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 29. | cal/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; M |
By formula: (S2- • CS2) + CS2 = (S2- • 2CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 6.1 | kcal/mol | PHPMS | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 20. | cal/mol*K | N/A | Hiraoka, Fujimaki, et al., 1994, 2 | gas phase; Entropy change calculated or estimated; M |
By formula: (S2- • 4294967295S) + S = S2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 92.7 ± 5.2 | kcal/mol | N/A | Moran and Ellison, 1988 | gas phase; B |
References
Go To: Top, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Moran and Ellison, 1988
Moran, S.; Ellison, G.B.,
Photoelectron Spectroscopy of Sulfur Ions,
J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021
. [all data]
Goodings, Bohme, et al., 1986
Goodings, J.M.; Bohme, D.K.; Elguindi, K.; Fox, A.,
Sulphur Anion Chemistry in Hydrocarbon Flames with H2S, OCS, and SO2 Additives,
Can. J. Chem., 1986, 64, 4, 689, https://doi.org/10.1139/v86-110
. [all data]
Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K.,
Frontier-controlled Structures of the Gas Phas Clusters A+/-(CS2)n, A+/- = S2+, CS2+, S2-, and CS2-,
J. Phys. Chem. (1994), 1994, 98, 7, 1802-1809, https://doi.org/10.1021/j100058a014
. [all data]
Hiraoka, Fujimaki, et al., 1994, 2
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S.,
Frontier-Controlled Structures of the Gas-Phase A+-(CS2)n Clusters ,A+- = S2+, CS2+, S2-, and CS2-,
J. Phys. Chem., 1994, 98, 7, 1802, https://doi.org/10.1021/j100058a014
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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