Phosphorus dimer


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas144.0 ± 2.0kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Δfgas143.65kJ/molReviewChase, 1998Data last reviewed in June, 1961
Quantity Value Units Method Reference Comment
gas,1 bar218.123 ± 0.004J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
gas,1 bar218.07J/mol*KReviewChase, 1998Data last reviewed in June, 1961

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 6000.
A 35.92198
B 1.483806
C -0.339811
D 0.028919
E -0.401919
F 131.5232
G 258.8557
H 143.6530
ReferenceChase, 1998
Comment Data last reviewed in June, 1961

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

(CAS Reg. No. 141171-05-3 • 4294967295Phosphorus dimer) + Phosphorus dimer = CAS Reg. No. 141171-05-3

By formula: (CAS Reg. No. 141171-05-3 • 4294967295P2) + P2 = CAS Reg. No. 141171-05-3

Quantity Value Units Method Reference Comment
Δr208. ± 32.kJ/molTherO'Hair, Krempp, et al., 1992gas phase; Acidity between MeNO2, tBuSH
Δr213. ± 21.kJ/molIMRBO'Hair, Krempp, et al., 1992gas phase; Hydride affinity: between CO2, SO2

(CAS Reg. No. 141171-04-2 • 4294967295Phosphorus dimer) + Phosphorus dimer = CAS Reg. No. 141171-04-2

By formula: (CAS Reg. No. 141171-04-2 • 4294967295P2) + P2 = CAS Reg. No. 141171-04-2

Quantity Value Units Method Reference Comment
Δr144. ± 10.kJ/molIMRBO'Hair, Krempp, et al., 1992gas phase; Fluoride affinity: Between H2S, MeSH
Δr138. ± 34.kJ/molTherO'Hair, Krempp, et al., 1992gas phase; Acidity between MeSH, H2S

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

O'Hair, Krempp, et al., 1992
O'Hair, R.A.J.; Krempp, M.; Damrauer, R.; Depuy, C.H., Gas-Phase Ion Chemistry of HP2(-), FP2(-), and HP2(+), Inorg. Chem., 1992, 31, 11, 2092, https://doi.org/10.1021/ic00037a021 . [all data]


Notes

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