Azide cation


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(N3+ • 10Nitrogen) + Nitrogen = (N3+ • 11Nitrogen)

By formula: (N3+ • 10N2) + N2 = (N3+ • 11N2)

Quantity Value Units Method Reference Comment
Δr1.4 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr16.9cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • 9Nitrogen) + Nitrogen = (N3+ • 10Nitrogen)

By formula: (N3+ • 9N2) + N2 = (N3+ • 10N2)

Quantity Value Units Method Reference Comment
Δr1.5 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr16.5cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • 3Nitrogen) + Nitrogen = (N3+ • 4Nitrogen)

By formula: (N3+ • 3N2) + N2 = (N3+ • 4N2)

Quantity Value Units Method Reference Comment
Δr3.7 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr23.2cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • 4Nitrogen) + Nitrogen = (N3+ • 5Nitrogen)

By formula: (N3+ • 4N2) + N2 = (N3+ • 5N2)

Quantity Value Units Method Reference Comment
Δr3.3 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr25.3cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • 5Nitrogen) + Nitrogen = (N3+ • 6Nitrogen)

By formula: (N3+ • 5N2) + N2 = (N3+ • 6N2)

Quantity Value Units Method Reference Comment
Δr2.4 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr21.2cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • 6Nitrogen) + Nitrogen = (N3+ • 7Nitrogen)

By formula: (N3+ • 6N2) + N2 = (N3+ • 7N2)

Quantity Value Units Method Reference Comment
Δr2.1 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr19.3cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • 7Nitrogen) + Nitrogen = (N3+ • 8Nitrogen)

By formula: (N3+ • 7N2) + N2 = (N3+ • 8N2)

Quantity Value Units Method Reference Comment
Δr1.8 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr16.7cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • 8Nitrogen) + Nitrogen = (N3+ • 9Nitrogen)

By formula: (N3+ • 8N2) + N2 = (N3+ • 9N2)

Quantity Value Units Method Reference Comment
Δr1.6 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr16.3cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • 2Nitrogen) + Nitrogen = (N3+ • 3Nitrogen)

By formula: (N3+ • 2N2) + N2 = (N3+ • 3N2)

Quantity Value Units Method Reference Comment
Δr4.1 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr21.4cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

(N3+ • Nitrogen) + Nitrogen = (N3+ • 2Nitrogen)

By formula: (N3+ • N2) + N2 = (N3+ • 2N2)

Quantity Value Units Method Reference Comment
Δr4.1 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr20.2cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

N3+ + Nitrogen = (N3+ • Nitrogen)

By formula: N3+ + N2 = (N3+ • N2)

Quantity Value Units Method Reference Comment
Δr4.5 ± 0.3kcal/molPHPMSHiraoka and Yamabe, 1989gas phase
Quantity Value Units Method Reference Comment
Δr20.0cal/mol*KPHPMSHiraoka and Yamabe, 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1989
Hiraoka, K.; Yamabe, S., Stabilities of the N3+(N2)n Cluster Ions with n = 1 - 11, Chem. Phys. Lett., 1989, 154, 2, 139, https://doi.org/10.1016/S0009-2614(89)87275-6 . [all data]


Notes

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