Hydrogen anion

• Formula: H^-
• Molecular weight: 1.00849
• IUPAC Standard InChI: InChI=1S/H/q-1 Copy

  
• IUPAC Standard InChIKey: KLGZELKXQMTEMM-UHFFFAOYSA-N Copy
• CAS Registry Number: 12184-88-2
• Chemical structure:
  This structure is also available as a 2d Mol file
• Isotopologues:
  • Deuterium anion
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Options:
  • Switch to SI units

Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  =

By formula: H^- + H⁺ = H₂

 +  = ( • )

By formula: H^- + H₃B = (H^- • H₃B)

 +  = ( • )

By formula: H^- + H₂O = (H^- • H₂O)

 + CAS Reg. No. 10177-98-7 = ( • CAS Reg. No. 10177-98-7)

By formula: H^- + CAS Reg. No. 10177-98-7 = (H^- • CAS Reg. No. 10177-98-7)

 +  = ( • )

By formula: H^- + C₆H₁₆Si = (H^- • C₆H₁₆Si)

 +  = ( • )

By formula: H^- + H₄Si = (H^- • H₄Si)

 +  = ( • )

By formula: H^- + C₄H₁₂Si = (H^- • C₄H₁₂Si)

 +  = ( • )

By formula: H^- + H₃N = (H^- • H₃N)

 +  = ( • )

By formula: H^- + C₃H₉Al = (H^- • C₃H₉Al)

( • ) +  = ( • 2)

By formula: (H^- • H₃N) + H₃N = (H^- • 2H₃N)

 +  = ( • )

By formula: H^- + O₂S = (H^- • O₂S)

 +  = ( • )

By formula: H^- + C₆H₁₅B = (H^- • C₆H₁₅B)

 +  = ( • )

By formula: H^- + C₆MoO₆ = (H^- • C₆MoO₆)

 +  = ( • )

By formula: H^- + C₆O₆W = (H^- • C₆O₆W)

 +  = ( • )

By formula: H^- + H₆B₂ = (H^- • H₆B₂)

= C₇H₁₅O^-

By formula: H^- = C₇H₁₅O^-

 + CH₂BN = ( • CH₂BN)

By formula: H^- + CH₂BN = (H^- • CH₂BN)

= C₇H₁₃O^-

By formula: H^- = C₇H₁₃O^-

 +  = ( • )

By formula: H^- + C₅FeO₅ = (H^- • C₅FeO₅)

 +  = ( • )

By formula: H^- + HO = (H^- • HO)

 + H₆Al₂ = H₇Al₂^-

By formula: H^- + H₆Al₂ = H₇Al₂^-

 +  = H₄Al^-

By formula: H^- + H₃Al = H₄Al^-

 +  = C₆H₆F₃Si^-

By formula: H^- + C₆H₅F₃Si = C₆H₆F₃Si^-

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

 +  =

By formula: H^- + H⁺ = H₂

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

= C₇H₁₃O^-

By formula: H^- = C₇H₁₃O^-

= C₇H₁₅O^-

By formula: H^- = C₇H₁₅O^-

 + CH₂BN = ( • CH₂BN)

By formula: H^- + CH₂BN = (H^- • CH₂BN)

 +  = ( • )

By formula: H^- + C₃H₉Al = (H^- • C₃H₉Al)

 +  = ( • )

By formula: H^- + C₄H₁₂Si = (H^- • C₄H₁₂Si)

 +  = ( • )

By formula: H^- + C₅FeO₅ = (H^- • C₅FeO₅)

 +  = C₆H₆F₃Si^-

By formula: H^- + C₆H₅F₃Si = C₆H₆F₃Si^-

 +  = ( • )

By formula: H^- + C₆H₁₅B = (H^- • C₆H₁₅B)

 +  = ( • )

By formula: H^- + C₆H₁₆Si = (H^- • C₆H₁₆Si)

 +  = ( • )

By formula: H^- + C₆MoO₆ = (H^- • C₆MoO₆)

 +  = ( • )

By formula: H^- + C₆O₆W = (H^- • C₆O₆W)

 +  = ( • )

By formula: H^- + HO = (H^- • HO)

 +  = ( • )

By formula: H^- + H₂O = (H^- • H₂O)

 +  = H₄Al^-

By formula: H^- + H₃Al = H₄Al^-

 +  = ( • )

By formula: H^- + H₃B = (H^- • H₃B)

 +  = ( • )

By formula: H^- + H₃N = (H^- • H₃N)

( • ) +  = ( • 2)

By formula: (H^- • H₃N) + H₃N = (H^- • 2H₃N)

 +  = ( • )

By formula: H^- + H₄Si = (H^- • H₄Si)

 + H₆Al₂ = H₇Al₂^-

By formula: H^- + H₆Al₂ = H₇Al₂^-

 +  = ( • )

By formula: H^- + H₆B₂ = (H^- • H₆B₂)

 +  = ( • )

By formula: H^- + O₂S = (H^- • O₂S)

 + CAS Reg. No. 10177-98-7 = ( • CAS Reg. No. 10177-98-7)

By formula: H^- + CAS Reg. No. 10177-98-7 = (H^- • CAS Reg. No. 10177-98-7)

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Shiell, Hu, et al., 2000
Shiell, R.C.; Hu, X.K.; Hu, Q.C.J.; Hepburn, J.W., Threshold Ion-pair Production spectroscopy (TIPPS) of H2 and D2, Faraday Disc. Chem. Soc., 2000, 115, 331, https://doi.org/10.1039/a909428h . [all data]

Pratt, McCormack, et al., 1992
Pratt, S.T.; McCormack, E.F.; Dehmer, J.L.; Dehmer, P.M., Field-Induced Ion-Pair Formation in Molecular Hydrogen, Phys. Rev. Lett., 1992, 68, 5, 584, https://doi.org/10.1103/PhysRevLett.68.584 . [all data]

Gurvich, Veyts, et al.
Gurvich, L.V.; Veyts, I.V.; Alcock, C.B., Hemisphere Publishing, NY, 1989, V. 1 2, Thermodynamic Properties of Individual Substances, 4th Ed. [all data]

Lykke, Murray, et al., 1991
Lykke, K.R.; Murray, K.K.; Lineberger, W.C., Threshold Photodetachment of H-, Phys. Rev. A, 1991, 43, 11, 6104, https://doi.org/10.1103/PhysRevA.43.6104 . [all data]

Workman and Squires, 1988
Workman, D.B.; Squires, R.R., Hydride Binding Energies of Boranes, Inorg. Chem., 1988, 27, 11, 1846, https://doi.org/10.1021/ic00284a003 . [all data]

Krivtsov, Titova, et al., 1977
Krivtsov, N.V.; Titova, K.V.; Rosolovskii, V.Ya., Thermochemical study of complex borates, Russ. J. Inorg. Chem., 1977, 22, 374. [all data]

Altschuller, 1955
Altschuller, A.P., Lattice Energies and Related Thermodynamic Properties of the Alkali Metal Borohydrides and of the Borohydride Ion, J. Am. Chem. Soc., 1955, 77, 21, 5455, https://doi.org/10.1021/ja01626a001 . [all data]

Miller, Leopold, et al., 1985
Miller, T.M.; Leopold, D.G.; Murray, K.K.; Lineberger, W.C., The Photoelectron Spectrum of H3O-, Bull. Am. Phys. Soc., 1985, 30, 880. [all data]

Paulson and Henchman, 1984
Paulson, J.F.; Henchman, M.J., On the Formation of H₃O^- in an Ion-Molecule Reaction in Ionic Processes in the Gas Phase,, M.A. Almoster Ferreira, Ed., Reidel, Dordrecht,, 1984, 331. [all data]

Griffiths and Harris, 1989
Griffiths, W.J.; Harris, F.M., Amended Interpretation of the Results Obtained in an Experimental Investigation of the Structure of the H3O- Ion, Int. J. Mass Spectrom. Ion Proc., 1989, 87, 1, R25, https://doi.org/10.1016/0168-1176(89)80017-5 . [all data]

Paulson and Henchman, 1982
Paulson, J.F.; Henchman, M.J., The Hydrated Negative Hydrogen Ion, Bull. Am. Phys. Soc., 1982, 27, 108. [all data]

Hajdasz, Ho, et al., 1994
Hajdasz, D.J.; Ho, Y.; Squires, R.R., Gas-Phase Chemistry of Pentacoordinate Silicon Hydrides, J. Am. Chem. Soc., 1994, 116, 23, 10751, https://doi.org/10.1021/ja00102a045 . [all data]

Hajdasz and Squires, 1986
Hajdasz, D.J.; Squires, R.R., Hypervalent silicon hydrides: SiH₅^-, J. Am. Chem. Soc., 1986, 108, 3139. [all data]

Snodgrass, Coe, et al., 1995
Snodgrass, J.T.; Coe, J.V.; Freidhoff, C.B.; Mchugh, K.M.; Arnold, S.T.; Bowen, K.H., Negative ion photoelectron spectroscopy of NH2-(NH3)1 and NH2-(NH3)2: Gas phase basicities of partially solvated anions, J. Phys. Chem., 1995, 99, 24, 9675, https://doi.org/10.1021/j100024a006 . [all data]

Coe, Snodgrass, et al., 1985
Coe, J.V.; Snodgrass, J.T.; Friedhoff, C.B.; McHugh, K.M.; Bowen, K.H., Negative ion photoelectron spectroscopy of the negative ion H-(NH₃), J. Chem. Phys., 1985, 83, 3169. [all data]

den Berg, Ingemann, et al., 1992
den Berg, K.J. van; Ingemann, S.; Nibbering, N.M.M., Gas Phase Reactions of Negative Ions with Trimethylaluminum: Formation and Reactivity of the Me3AlH- Ion., Org. Mass Spectrom., 1992, 27, 4, 523, https://doi.org/10.1002/oms.1210270427 . [all data]

Sheldon, Currie, et al., 1985
Sheldon, J.C.; Currie, G.J.; Lahnstein, J.; Hayes, R.N.; Bowie, J.H., Gas Phase Ion Chemistry of Ambident Nucleophiles. Reactions of Alkoxide and Thiomethoxide Negative Ions with Hydrogen Free Molecules., Nouv. J. Chem., 1985, 9, 205. [all data]

Lane and Squires, 1988
Lane, K.R.; Squires, R.R., Hydride Transfer to Transition Metal Carbonyls in the Gas Phase. Formation and Relative Stabilities of Anionic Formyl Complexes, Polyhedron, 1988, 7, 16-17, 1609, https://doi.org/10.1016/S0277-5387(00)81786-6 . [all data]

Boand, Houriet, et al., 1983
Boand, G.; Houriet, R.; Baumann, T., The gas phase acidity of aliphatic alcohols, J. Am. Chem. Soc., 1983, 105, 2203. [all data]

Haas and Harrison, 1993
Haas, M.J.; Harrison, A.G., The Fragmentation of Proton-Bound Cluster Ions and the Gas-Phase Acidities of Alcohols, Int. J. Mass Spectrom. Ion Proc., 1993, 124, 2, 115, https://doi.org/10.1016/0168-1176(93)80003-W . [all data]

Lane, Sallans, et al., 1985
Lane, K.R.; Sallans, L.; Squires, R.R., Anion affinities of transition metal carbonyls. A thermochemical correlation for iron tetracarbonyl acyl negative ions, J. Am. Chem. Soc., 1985, 107, 5369. [all data]

de Koening and Nibbering, 1984
de Koening, L.J.; Nibbering, N.M.M., Formation of the Long-Lived H₂O^-. Ion in the Gas Phase, J. Am. Chem. Soc., 1984, 106, 25, 7971, https://doi.org/10.1021/ja00337a054 . [all data]

Goebbert, Hernandez, et al., 2005
Goebbert, D.J.; Hernandez, H.; Francisco, J.S.; Wenthold, P.G., The binding energy and bonding in dialane, J. Am. Chem. Soc., 2005, 127, 33, 11684-11689, https://doi.org/10.1021/ja0424070 . [all data]

Krouse, Lardin, et al., 2003
Krouse, I.H.; Lardin, H.A.; Wenthold, P.G., Gas-phase ion chemistry and ion thermochemistry of phenyltrifluorosilane, Int. J. Mass Spectrom., 2003, 227, 3, 303-314, https://doi.org/10.1016/S1387-3806(03)00080-0 . [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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