Dichlorobis(η5-2,4-cyclopentadien-1-yl)molybdenium
- Formula: C10H10Cl2Mo
- Molecular weight: 297.05
- CAS Registry Number: 12184-22-4
- Information on this page:
- Other data available:
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 4.1 ± 5.1 | kJ/mol | Review | Martinho Simões | Selected data |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -96.3 ± 2.9 | kJ/mol | Review | Martinho Simões | Selected data |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -6059.3 ± 2.5 | kJ/mol | CC-SB | Tel'noi, Rabinovich, et al., 1976 | Please also see Tel'noi and Rabinovich, 1977. |
Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C12H16Mo (cr) + 2( • 5.55
) (solution) = C10H10Cl2Mo (cr) + 2
(g)
By formula: C12H16Mo (cr) + 2(HCl • 5.55H2O) (solution) = C10H10Cl2Mo (cr) + 2CH4 (g)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -193.6 ± 3.0 | kJ/mol | RSC | Calado, Dias, et al., 1978 | Please also see Calhorda, Dias, et al., 1987. |
C14H10F6MoO4 (cr) + 2( • 4.40
) (solution) = C10H10Cl2Mo (cr) + 2
(l)
By formula: C14H10F6MoO4 (cr) + 2(HCl • 4.40H2O) (solution) = C10H10Cl2Mo (cr) + 2C2HF3O2 (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 58.2 ± 2.5 | kJ/mol | RSC | Calado, Dias, et al., 1981 | Please also see Calhorda, Carrondo, et al., 1986. |
C10H12Mo (cr) + 2 (l) = C10H10Cl2Mo (cr) + 2
(l)
By formula: C10H12Mo (cr) + 2CCl4 (l) = C10H10Cl2Mo (cr) + 2CHCl3 (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -321.3 ± 4.4 | kJ/mol | RSC | Calado, Dias, et al., 1979 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Tel'noi, Rabinovich, et al., 1976
Tel'noi, V.I.; Rabinovich, I.B.; Kir'yanov, K.V.; Smirnov, A.S.,
Dokl. Akad. Nauk SSSR, 1976, 231, 733. [all data]
Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B.,
Russ. Chem. Rev., 1977, 46, 689. [all data]
Calado, Dias, et al., 1978
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V.,
J. Chem. Soc., Chem. Commun., 1978, 737.. [all data]
Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A.,
Organometallics, 1987, 6, 734. [all data]
Calado, Dias, et al., 1981
Calado, J.C.G.; Dias, A.R.; Salema, M.S.; Martinho Simões, J.A.,
J. Chem. Soc., Dalton Trans., 1981, 1174.. [all data]
Calhorda, Carrondo, et al., 1986
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Domingos, A.M.T.S.; Martinho Simões, J.A.; Teixeira, C.,
Organometallics, 1986, 5, 660. [all data]
Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V.,
J. Organometal. Chem., 1979, 174, 77. [all data]
Notes
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- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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