Dichlorobis(η5-2,4-cyclopentadien-1-yl)molybdenium


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub100.4 ± 4.2kJ/molETel'noi, Rabinovich, et al., 1976AC
Δsub100.4 ± 4.2kJ/molCC-SBTel'noi, Rabinovich, et al., 1976MS

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C12H16Mo (cr) + 2(Hydrogen chloride • 5.55Water) (solution) = C10H10Cl2Mo (cr) + 2Methane (g)

By formula: C12H16Mo (cr) + 2(HCl • 5.55H2O) (solution) = C10H10Cl2Mo (cr) + 2CH4 (g)

Quantity Value Units Method Reference Comment
Δr-193.6 ± 3.0kJ/molRSCCalado, Dias, et al., 1978Please also see Calhorda, Dias, et al., 1987.

C14H10F6MoO4 (cr) + 2(Hydrogen chloride • 4.40Water) (solution) = C10H10Cl2Mo (cr) + 2Trifluoroacetic acid (l)

By formula: C14H10F6MoO4 (cr) + 2(HCl • 4.40H2O) (solution) = C10H10Cl2Mo (cr) + 2C2HF3O2 (l)

Quantity Value Units Method Reference Comment
Δr58.2 ± 2.5kJ/molRSCCalado, Dias, et al., 1981Please also see Calhorda, Carrondo, et al., 1986.

C10H12Mo (cr) + 2Carbon Tetrachloride (l) = C10H10Cl2Mo (cr) + 2Trichloromethane (l)

By formula: C10H12Mo (cr) + 2CCl4 (l) = C10H10Cl2Mo (cr) + 2CHCl3 (l)

Quantity Value Units Method Reference Comment
Δr-321.3 ± 4.4kJ/molRSCCalado, Dias, et al., 1979 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Tel'noi, Rabinovich, et al., 1976
Tel'noi, V.I.; Rabinovich, I.B.; Kir'yanov, K.V.; Smirnov, A.S., Dokl. Akad. Nauk SSSR, 1976, 231, 733. [all data]

Calado, Dias, et al., 1978
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Chem. Soc., Chem. Commun., 1978, 737.. [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]

Calado, Dias, et al., 1981
Calado, J.C.G.; Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., J. Chem. Soc., Dalton Trans., 1981, 1174.. [all data]

Calhorda, Carrondo, et al., 1986
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Domingos, A.M.T.S.; Martinho Simões, J.A.; Teixeira, C., Organometallics, 1986, 5, 660. [all data]

Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Organometal. Chem., 1979, 174, 77. [all data]


Notes

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