Dichlorobis(η5-2,4-cyclopentadien-1-yl)molybdenium


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-96.3 ± 2.9kJ/molReviewMartinho SimõesSelected data
Quantity Value Units Method Reference Comment
Δcsolid-6059.3 ± 2.5kJ/molCC-SBTel'noi, Rabinovich, et al., 1976Please also see Tel'noi and Rabinovich, 1977.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

C12H16Mo (cr) + 2(Hydrogen chloride • 5.55Water) (solution) = C10H10Cl2Mo (cr) + 2Methane (g)

By formula: C12H16Mo (cr) + 2(HCl • 5.55H2O) (solution) = C10H10Cl2Mo (cr) + 2CH4 (g)

Quantity Value Units Method Reference Comment
Δr-193.6 ± 3.0kJ/molRSCCalado, Dias, et al., 1978Please also see Calhorda, Dias, et al., 1987.

C14H10F6MoO4 (cr) + 2(Hydrogen chloride • 4.40Water) (solution) = C10H10Cl2Mo (cr) + 2Trifluoroacetic acid (l)

By formula: C14H10F6MoO4 (cr) + 2(HCl • 4.40H2O) (solution) = C10H10Cl2Mo (cr) + 2C2HF3O2 (l)

Quantity Value Units Method Reference Comment
Δr58.2 ± 2.5kJ/molRSCCalado, Dias, et al., 1981Please also see Calhorda, Carrondo, et al., 1986.

C10H12Mo (cr) + 2Carbon Tetrachloride (l) = C10H10Cl2Mo (cr) + 2Trichloromethane (l)

By formula: C10H12Mo (cr) + 2CCl4 (l) = C10H10Cl2Mo (cr) + 2CHCl3 (l)

Quantity Value Units Method Reference Comment
Δr-321.3 ± 4.4kJ/molRSCCalado, Dias, et al., 1979 

References

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Tel'noi, Rabinovich, et al., 1976
Tel'noi, V.I.; Rabinovich, I.B.; Kir'yanov, K.V.; Smirnov, A.S., Dokl. Akad. Nauk SSSR, 1976, 231, 733. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]

Calado, Dias, et al., 1978
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Chem. Soc., Chem. Commun., 1978, 737.. [all data]

Calhorda, Dias, et al., 1987
Calhorda, M.J.; Dias, A.R.; Minas da Piedade M.E.; Salema, M.S.; Martinho Simões J.A., Organometallics, 1987, 6, 734. [all data]

Calado, Dias, et al., 1981
Calado, J.C.G.; Dias, A.R.; Salema, M.S.; Martinho Simões, J.A., J. Chem. Soc., Dalton Trans., 1981, 1174.. [all data]

Calhorda, Carrondo, et al., 1986
Calhorda, M.J.; Carrondo, M.A.A.F.C.T.; Dias, A.R.; Domingos, A.M.T.S.; Martinho Simões, J.A.; Teixeira, C., Organometallics, 1986, 5, 660. [all data]

Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V., J. Organometal. Chem., 1979, 174, 77. [all data]


Notes

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