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Benzene, nitro- anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Individual Reactions

C6H5NO2- + Methyl Alcohol = (C6H5NO2- bullet Methyl Alcohol)

By formula: C6H5NO2- + CH4O = (C6H5NO2- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar63.18 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.5 ± 1.7kJ/molTDAsSieck, 1985gas phase; B
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Dimethyl Sulfoxide = (C6H5NO2- bullet Dimethyl Sulfoxide)

By formula: C6H5NO2- + C2H6OS = (C6H5NO2- bullet C2H6OS)

Quantity Value Units Method Reference Comment
Deltar70.29 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar39.7 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Deltar36. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

(C6H5NO2- bullet Water) + Water = (C6H5NO2- bullet 2Water)

By formula: (C6H5NO2- bullet H2O) + H2O = (C6H5NO2- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar51.88 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar20.9 ± 1.7kJ/molTDAsSieck, 1985gas phase; B

C6H5NO2- + Water = (C6H5NO2- bullet Water)

By formula: C6H5NO2- + H2O = (C6H5NO2- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar56.48 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.3 ± 0.84kJ/molTDAsSieck, 1985gas phase; B

C6H5NO2- + Acetic acid = (C6H5NO2- bullet Acetic acid)

By formula: C6H5NO2- + C2H4O2 = (C6H5NO2- bullet C2H4O2)

Quantity Value Units Method Reference Comment
Deltar94.56 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar61.09 ± 0.84kJ/molTDAsSieck, 1985gas phase; B

C6H5NO2- + Acetone = (C6H5NO2- bullet Acetone)

By formula: C6H5NO2- + C3H6O = (C6H5NO2- bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar59.41 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.8 ± 1.7kJ/molTDAsSieck, 1985gas phase; B

C6H5NO2- + Tetrahydrofuran = (C6H5NO2- bullet Tetrahydrofuran)

By formula: C6H5NO2- + C4H8O = (C6H5NO2- bullet C4H8O)

Quantity Value Units Method Reference Comment
Deltar13. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 35°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.308.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Formamide, N,N-dimethyl- = (C6H5NO2- bullet Formamide, N,N-dimethyl-)

By formula: C6H5NO2- + C3H7NO = (C6H5NO2- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar26. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
26.343.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Acetonitrile = (C6H5NO2- bullet Acetonitrile)

By formula: C6H5NO2- + C2H3N = (C6H5NO2- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar28. ± 6.7kJ/molIMREChowdhury, Grimsrud, et al., 1987gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
28.343.PHPMSChowdhury, 1987gas phase; M

C6H5NO2- + Silicon tetrafluoride = C6H5F4NO2Si-

By formula: C6H5NO2- + F4Si = C6H5F4NO2Si-

Quantity Value Units Method Reference Comment
Deltar146. ± 8.4kJ/molTDAsWilliamson, Knighton, et al., 2001gas phase; at 150 C; B
Quantity Value Units Method Reference Comment
Deltar64.9 ± 2.5kJ/molTDAsWilliamson, Knighton, et al., 2001gas phase; at 150 C; B

C6H5NO2- + 2-Propanol, 2-methyl- = (C6H5NO2- bullet 2-Propanol, 2-methyl-)

By formula: C6H5NO2- + C4H10O = (C6H5NO2- bullet C4H10O)

Quantity Value Units Method Reference Comment
Deltar68.6kJ/molPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSSieck, 1985gas phase; M

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sieck, 1985
Sieck, L.W., Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure., J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049 . [all data]

Chowdhury, Grimsrud, et al., 1987
Chowdhury, S.; Grimsrud, E.P.; Kebarle, P., Bonding of Charged Delocalized Anions to Protic and Dipolar Aprotic Solvent Molecules, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Chowdhury, 1987
Chowdhury, S. Grimsrud, Bonding of Charge Delocalized Anions to Protic and Dipolar Aprotic Solvents, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Williamson, Knighton, et al., 2001
Williamson, D.H.; Knighton, W.B.; Grimsrud, E.P., Lewis acid-base interactions of SiF4 with molecular anions formed by electron capture reactions, Int. J. Mass Spectrom., 2001, 206, 1-2, 53-61, https://doi.org/10.1016/S1387-3806(00)00388-2 . [all data]


Notes

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