Triethylamine
- Formula: C6H15N
- Molecular weight: 101.1900
- IUPAC Standard InChIKey: ZMANZCXQSJIPKH-UHFFFAOYSA-N
- CAS Registry Number: 121-44-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Ethanamine, N,N-diethyl-; (C2H5)3N; (Diethylamino)ethane; N,N-Diethylethanamine; TEN; Triaethylamin; Trietilamina; UN 1296; 1069-58-5 (maleate); 554-68-7 (chloride)
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Normal boiling point
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
Tboil (K) | Reference | Comment |
---|---|---|
362.0 | Stephenson, 1993 | Uncertainty assigned by TRC = 1. K; TRC |
362.5 | Weast and Grasselli, 1989 | BS |
362.1 | Majer and Svoboda, 1985 | |
362.35 | Letcher and Bayles, 1971 | Uncertainty assigned by TRC = 0.3 K; TRC |
362.3 | Christie and Crisp, 1967 | Uncertainty assigned by TRC = 0.5 K; Extrapolated from observed vapor pressure data.; TRC |
362.6 | Humphrey and Van Winkle, 1967 | Uncertainty assigned by TRC = 0.15 K; TRC |
362.55 | Lempe, Neuhaeuser, et al., 1966 | Uncertainty assigned by TRC = 0.4 K; TRC |
362. | Bittrich, Kauer, et al., 1962 | Uncertainty assigned by TRC = 0.5 K; log p = 45.0133 - 2549.5/T - 12.54 log T; TRC |
362.72 | Copp and Findlay, 1960 | Uncertainty assigned by TRC = 0.1 K; TRC |
362.55 | Costello and Bowden, 1959 | Uncertainty assigned by TRC = 1. K; TRC |
362.35 | Holmes and Bertaut, 1958 | Uncertainty assigned by TRC = 0.5 K; TRC |
362.55 | Kohler and Rice, 1957 | Uncertainty assigned by TRC = 0.3 K; TRC |
362.15 | Blout and Karlson, 1956 | Uncertainty assigned by TRC = 1.5 K; TRC |
362.05 | Neckel and Kohler, 1956 | Uncertainty assigned by TRC = 0.3 K; TRC |
361.95 | Shirai, 1956 | Uncertainty assigned by TRC = 0.5 K; TRC |
362.4 | Schneider, Adkins, et al., 1952 | Uncertainty assigned by TRC = 0.7 K; TRC |
362.05 | Young, Webb, et al., 1951 | Uncertainty assigned by TRC = 0.5 K; TRC |
361.65 | Dilke, Eley, et al., 1950 | Uncertainty assigned by TRC = 0.6 K; TRC |
362.15 | Utter and Schlittler, 1948 | Uncertainty assigned by TRC = 3. K; TRC |
362.65 | Borrows, Hargreaves, et al., 1947 | Uncertainty assigned by TRC = 2. K; TRC |
362.15 | Watt and Otto, 1947 | Uncertainty assigned by TRC = 1. K; TRC |
363.65 | Prevost and Cerf de Mauny, 1943 | Uncertainty assigned by TRC = 2. K; TRC; Data excluded from overall average |
361.65 | Wittig and Merkle, 1943 | Uncertainty assigned by TRC = 2. K; TRC |
362.15 | Ewell and Welch, 1941 | Uncertainty assigned by TRC = 1. K; TRC |
361.9 | Perrin and Williams, 1937 | Uncertainty assigned by TRC = 1. K; TRC |
362.5 | Timmermans and Hennaut-Roland, 1932 | Uncertainty assigned by TRC = 0.3 K; TRC |
362.05 | Herz and Neukirch, 1923 | Uncertainty assigned by TRC = 0.3 K; TRC |
362.55 | Timmermans, 1914 | Uncertainty assigned by TRC = 0.2 K; not clear that this is a new measurement; TRC |
361.15 | Gaudion, 1912 | Uncertainty assigned by TRC = 3. K; TRC; Data excluded from overall average |
362.15 | Perkin, 1889 | Uncertainty assigned by TRC = 2. K; TRC |
References
Go To: Top, Normal boiling point, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson, 1993
Stephenson, R.M.,
Mutual Solubility of Water and Aliphatic Amines,
J. Chem. Eng. Data, 1993, 38, 625-9. [all data]
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Letcher and Bayles, 1971
Letcher, T.M.; Bayles, J.W.,
Thermodyn. Of some Binary Liquid Mixtures Containing Aliphatic Amines,
J. Chem. Eng. Data, 1971, 16, 266. [all data]
Christie and Crisp, 1967
Christie, A.O.; Crisp, D.J.,
Activity coefficients of the n-primary, secondary and tertiary aliphatic amines in aqueous solution,
J. Appl. Chem., 1967, 17, 11. [all data]
Humphrey and Van Winkle, 1967
Humphrey, J.L.; Van Winkle, M.,
Vapor-Liquid Equilibria at 60 deg C for n-Hexane-Alkyl Amines and 1-Hexene- Alkyl AMines,
J. Chem. Eng. Data, 1967, 12, 526. [all data]
Lempe, Neuhaeuser, et al., 1966
Lempe, D.; Neuhaeuser, S.; Maeder, H.J.; Bittrich, H.-J.,
Equilibriums in Ternary Liquid-Liquid Systems; Triethylamine + Water and Monoethylamine, Diethylamine, and Hydrazine,
Wiss. Z. Tech. Hochsch. Chem. "Carl Schorlemmer" Leuna-Me- rseburg, 1966, 8, 158. [all data]
Bittrich, Kauer, et al., 1962
Bittrich, H.-J.; Kauer, E.; Kraft, M.; Schoppe, G.; Soll, W.; Ullrich, A.,
The Vapor Pressures of the Ethylamines,
J. Prakt. Chem., 1962, 17, 250. [all data]
Copp and Findlay, 1960
Copp, J.L.; Findlay, T.J.V.,
Thermodynamics of Binary Systems Containing Amines. Part 4.,
Trans. Faraday Soc., 1960, 56, 13. [all data]
Costello and Bowden, 1959
Costello, J.M.; Bowden, S.T.,
The Temperature Variation of Orthobaric Density Difference in Liquid-Vapour Systems. V. Amines,
Recl. Trav. Chim. Pays-Bas, 1959, 78, 391. [all data]
Holmes and Bertaut, 1958
Holmes, R.R.; Bertaut, E.F.,
The Reactions of Phosphorous and Antimony Chlorides with Trimethyl- amine, Triethylamine and Trimethylphosphine,
J. Am. Chem. Soc., 1958, 80, 2980. [all data]
Kohler and Rice, 1957
Kohler, F.; Rice, O.K.,
Coexistence curve of the triethylamine + water system,
J. Chem. Phys., 1957, 26, 1614-8. [all data]
Blout and Karlson, 1956
Blout, E.R.; Karlson, R.H.,
Polypeptides: III the synthesis of high molecular weight poly-gamma-benzyl- l-glutamates,
J. Am. Chem. Soc., 1956, 78, 941. [all data]
Neckel and Kohler, 1956
Neckel, A.; Kohler, F.,
Thermodynamics of binary mixtures of components of an approximately equal molar volume: II total pressures and activity coeffcients of the systems: 1,2,4-trichlorobenzene + n-hexane, trimethyl amine,
Monatsh. Chem., 1956, 87, 176. [all data]
Shirai, 1956
Shirai, M.,
Bull. Chem. Soc. Jpn., 1956, 29, 518. [all data]
Schneider, Adkins, et al., 1952
Schneider, H.-J.; Adkins, H.; McElvain, S.M.,
The Hydrogenation of Amides and Ammonium Salts. The Transalkylation of Tertiary Amines,
J. Am. Chem. Soc., 1952, 74, 4287. [all data]
Young, Webb, et al., 1951
Young, W.G.; Webb, I.D.; Goering, H.L.,
J. Am. Chem. Soc., 1951, 73, 1076. [all data]
Dilke, Eley, et al., 1950
Dilke, M.H.; Eley, D.D.; Sheppard, M.G.,
A survey of heats of mixing of some organic compounds with aluminum chloride,
Trans. Faraday Soc., 1950, 46, 261. [all data]
Utter and Schlittler, 1948
Utter; Schlittler,
Helv. Chim. Acta, 1948, 31, 1397. [all data]
Borrows, Hargreaves, et al., 1947
Borrows, E.T.; Hargreaves, B.M.C.; Page, J.E.; Resuggan, J.C.L.; Robinson, F.A.,
Preparation and Properties of Some Long Chain Aliphatic Amines,
J. Chem. Soc., 1947, 1947, 197. [all data]
Watt and Otto, 1947
Watt; Otto,
J. Am. Chem. Soc., 1947, 69, 836. [all data]
Prevost and Cerf de Mauny, 1943
Prevost, C.; Cerf de Mauny, H.,
C. R. Hebd. Seances Acad. Sci., 1943, 216, 771. [all data]
Wittig and Merkle, 1943
Wittig, G.; Merkle, W.,
Action of Tertiary AMines on Fluorobenzene in the Presence of Phenyllithium,
Chem. Ber., 1943, 76, 109. [all data]
Ewell and Welch, 1941
Ewell, R.H.; Welch, L.M.,
Maximum Boiling Mixtures of chloroparaffins with Donor Liquids,
J. Am. Chem. Soc., 1941, 63, 2475. [all data]
Perrin and Williams, 1937
Perrin; Williams,
Proc. R. Soc. London, A, 1937, 159, 162. [all data]
Timmermans and Hennaut-Roland, 1932
Timmermans, J.; Hennaut-Roland, M.,
The Work of the International Bureau of Physical-Chemical Standards. V. Study of the Physical Constants of Twenty Organic Compounds.,
J. Chim. Phys. Phys.-Chim. Biol., 1932, 29, 529-68. [all data]
Herz and Neukirch, 1923
Herz, W.; Neukirch, E.,
On Knowldge of the Critical State,
Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1923, 104, 433-50. [all data]
Timmermans, 1914
Timmermans, J.,
Freezing temperature of organic compounds. II.,
Bull. Soc. Chim. Belg., 1914, 27, 334. [all data]
Gaudion, 1912
Gaudion, G.,
Ann. Chim. Phys., 1912, 25, 125. [all data]
Perkin, 1889
Perkin, W.H.,
The Magneto Rotatory Power of Nitrogne Compounds. also of Hydrochloric Hydrobromic and Hydroioidic Acids and of some of the Salts of Ammonia and the Compound Ammonias,
J. Chem. Soc., 1889, 55, 680. [all data]
Notes
Go To: Top, Normal boiling point, References
- Symbols used in this document:
Tboil Boiling point - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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