Molybdenum, tricarbonylchloro(η5-2,4-cyclopentadien-1-yl)-
- Formula: C8H5ClMoO3
- Molecular weight: 280.54
- IUPAC Standard InChI: InChI=1S/C5H5.3CO.ClH.Mo/c1-2-4-5-3-1;3*1-2;;/h1-5H;;;;1H;/q;;;;;+1/p-1
- IUPAC Standard InChIKey: HNPPYXKLHDGBBD-UHFFFAOYSA-M
- CAS Registry Number: 12128-23-3
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Molybdenum, tricarbonylchloro-π-cyclopentadienyl-; Chlorotricarbonyl-π-cyclopentadienylmolybdenum; Tricarbonylchloro(cyclopentadienyl)molybdenum; Tricarbonylchloro-π-cyclopentadienylmolybdenum; Tricarbonylchloro(cyclopentadienyl)molibdenum
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C8H6MoO3 (solution) + (solution) =
(solution) +
(solution)
By formula: C8H6MoO3 (solution) + CCl4 (solution) = C8H5ClMoO3 (solution) + CHCl3 (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -31.81 ± 0.91 | kcal/mol | RSC | Nolan, López de la Vega, et al., 1986 | solvent: Tetrahydrofuran; The enthalpy of solution of Mo(Cp)(CO)3(H)(cr) was measured as 2.1 ± 0.1 kcal/mol Nolan, López de la Vega, et al., 1986, 2. Reaction temperature: 323 K |
Mass spectrum (electron ionization)
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | Penn State Mass Spectrom.Center |
| NIST MS number | 281410 |
References
Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D.,
J. Organometal. Chem., 1986, 315, 187. [all data]
Nolan, López de la Vega, et al., 1986, 2
Nolan, S.P.; López de la Vega, R.; Hoff, C.D.,
Organometallics, 1986, 5, 2529. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Mass spectrum (electron ionization), References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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