Ammonium Chloride

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfsolid-314.55kJ/molReviewChase, 1998Data last reviewed in September, 1965
Quantity Value Units Method Reference Comment
solid94.85J/mol*KReviewChase, 1998Data last reviewed in September, 1965

Solid Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 458.458. to 1500.
A 2101.470-64.43640
B -11194.40327.2270
C 23342.30-149.3460
D -16996.7024.39640
E -26.835306.432830
F -706.2010-281.0640
G 4937.300-24.41260
H -314.5530-314.5530
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in September, 1965 Data last reviewed in September, 1965

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub177.kJ/molN/ALuft, 1955 

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference
168.6550.ICallanan and Smith, 1971
176.6 ± 0.4308. to 363.TEWagner and Neumann, 1961

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Luft, 1955
Luft, N.W., Ind. Chemist, 1955, 31, 502. [all data]

Callanan and Smith, 1971
Callanan, Jane E.; Smith, Norman O., Sublimation pressures of solid solutions III. NH4Cl + NH4Br, The Journal of Chemical Thermodynamics, 1971, 3, 4, 531-538, https://doi.org/10.1016/S0021-9614(71)80036-8 . [all data]

Wagner and Neumann, 1961
Wagner, Horst; Neumann, Kurt, Der Dampfdruck des Ammoniumchlorids zwischen 35 und 90°C, Zeitschrift für Physikalische Chemie, 1961, 28, 12, 51-70, https://doi.org/10.1524/zpch.1961.28.12.051 . [all data]


Notes

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