Ammonium Chloride
- Formula: ClH4N
- Molecular weight: 53.491
- IUPAC Standard InChIKey: NLXLAEXVIDQMFP-UHFFFAOYSA-N
- CAS Registry Number: 12125-02-9
- Chemical structure:
This structure is also available as a 2d Mol file - Species with the same structure:
- Other names: (NH4)Cl; Ammonium chloride ((NH4)Cl); Amchlor; Ammoneric; Ammoniumchlorid; Ammonium muriate; Chlorid amonny; Darammon; SAL AMMONIA; SAL AMMONIAC; Salammonite; Salmiac; Ammonium chloride fume; Ammonium uriate; Katapone VV-328; Quaternary ammonium chloride
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | -75.179 | kcal/mol | Review | Chase, 1998 | Data last reviewed in September, 1965 |
Quantity | Value | Units | Method | Reference | Comment |
S°solid | 22.67 | cal/mol*K | Review | Chase, 1998 | Data last reviewed in September, 1965 |
Solid Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (cal/mol*K)
H° = standard enthalpy (kcal/mol)
S° = standard entropy (cal/mol*K)
t = temperature (K) / 1000.
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Temperature (K) | 298. to 458. | 458. to 1500. |
---|---|---|
A | 502.2634 | -15.40067 |
B | -2675.526 | 78.20913 |
C | 5578.944 | -35.69455 |
D | -4062.309 | 5.830880 |
E | -6.413791 | 1.537484 |
F | -168.7861 | -67.17591 |
G | 1180.043 | -5.834752 |
H | -75.17997 | -75.17997 |
Reference | Chase, 1998 | Chase, 1998 |
Comment | Data last reviewed in September, 1965 | Data last reviewed in September, 1965 |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 42.3 | kcal/mol | N/A | Luft, 1955 |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference |
---|---|---|---|
40.30 | 550. | I | Callanan and Smith, 1971 |
42.21 ± 0.1 | 308. to 363. | TE | Wagner and Neumann, 1961 |
Reaction thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
C9H27NSn3 (cr) + ( • 55) (solution) + 3 (l) = ( • 55) (solution) + 3C3H10OSn (cr)
By formula: C9H27NSn3 (cr) + (HCl • 55H2O) (solution) + 3H2O (l) = (H4ClN • 55H2O) (solution) + 3C3H10OSn (cr)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -70.20 ± 0.31 | kcal/mol | RSC | Baldwin, Lappert, et al., 1972 |
IR Spectrum
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Timothy J. Johnson, Tanya L. Myers, Yin-Fong Su, Russell G. Tonkyn, Molly Rose K. Kelly-Gorham, and Tyler O. Danby
Condensed Phase Spectrum
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Additional Data
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Particle size distribution data for this spectrum is available.
Owner | Public domain |
---|---|
Origin | Pacific Northwest National Laboratory Under IARPA Contract |
Date | March 2017 |
State | solid |
Instrument | Bruker Tensor 37 FTIR |
Aperture | 6 mm |
External diffuse reflectance accessory | A 562-G integrating sphere |
Beam splitter | Ge on KBr |
Diameter of detector port in sphere | 2×2 mm, 60° field of view MCT |
Sphere diameter | 75 mm |
Acquisition mode | double-sided, forward-backward |
Scanner velocity | 40 kHz |
Co-added scans | 2048 |
Phase resolution | 32.00 |
Phase correction | Mertz |
Zero filling | 4× |
Spectral range | 7,500 to 600 cm-1 saved; 7500 to 600 cm-1 reported |
Resolution | 0.96450084 |
Spectral resolution | 4 cm-1 |
Wavenumber accuracy | ± 0.4 cm-1 |
Apodization function | Blackman-Harris 3-term |
Low-pass filter | Open |
Switch gain on | 512 points |
Mass spectrum (electron ionization)
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | Japan AIST/NIMC Database- Spectrum MS-NW-9217 |
NIST MS number | 228589 |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Luft, 1955
Luft, N.W.,
Ind. Chemist, 1955, 31, 502. [all data]
Callanan and Smith, 1971
Callanan, Jane E.; Smith, Norman O.,
Sublimation pressures of solid solutions III. NH4Cl + NH4Br,
The Journal of Chemical Thermodynamics, 1971, 3, 4, 531-538, https://doi.org/10.1016/S0021-9614(71)80036-8
. [all data]
Wagner and Neumann, 1961
Wagner, Horst; Neumann, Kurt,
Der Dampfdruck des Ammoniumchlorids zwischen 35 und 90°C,
Zeitschrift für Physikalische Chemie, 1961, 28, 12, 51-70, https://doi.org/10.1524/zpch.1961.28.12.051
. [all data]
Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S.,
J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References
- Symbols used in this document:
S°solid Entropy of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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