Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)-
- Formula: C9H5O4V
- Molecular weight: 228.0751
- IUPAC Standard InChI: InChI=1S/C5H5.4CO.V/c1-2-4-5-3-1;4*1-2;/h1-5H;;;;;
- IUPAC Standard InChIKey: LIFGJKDEFQAOFY-UHFFFAOYSA-N
- CAS Registry Number: 12108-04-2
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Vanadium, tetracarbonyl-π-cyclopentadienyl-; Tetracarbonyl-π-cyclopentadienylvanadium; Tetracarbonylcyclopentadienylvanadium; Vanadium cyclopentadienyltetracarbonyl; Cyclopentadienylvanadium tetracarbonyl; tetracarbonyl(η5-cyclopenta-2,4-dien-1-yl)vanadium
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
(solution) +
(solution) = C15H21O3V (solution) +
(solution)
By formula: C9H5O4V (solution) + C7H16 (solution) = C15H21O3V (solution) + CO (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 25.6 ± 3.1 | kcal/mol | PAC | Johnson, Popov, et al., 1991 | solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation. |
(solution) +
(solution) = C8H7O3V (solution) +
(solution)
By formula: C9H5O4V (solution) + H2 (solution) = C8H7O3V (solution) + CO (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 13. ± 1. | kcal/mol | PAC | Johnson, Popov, et al., 1991 | solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation. |
(solution) +
(solution) = C8H5N2O3V (solution) +
(solution)
By formula: C9H5O4V (solution) + N2 (solution) = C8H5N2O3V (solution) + CO (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 6.5 ± 1. | kcal/mol | PAC | Johnson, Popov, et al., 1991 | solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation. |
(solution) +
(solution) =
(solution) +
(solution)
By formula: C9H5O4V (solution) + CO (solution) = C9H5O4V (solution) + CO (solution)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 0. ± 0.2 | kcal/mol | PAC | Johnson, Popov, et al., 1991 | solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation. |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Johnson, Popov, et al., 1991
Johnson, F.P.A.; Popov, V.K.; George, M.W.; Bagratashvili, V.N.; Poliakoff, M.; Turner, J.J.,
Mendeleev Commun., 1991, 145.. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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