Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Heptane (solution) = C15H21O3V (solution) + Carbon monoxide (solution)

By formula: C9H5O4V (solution) + C7H16 (solution) = C15H21O3V (solution) + CO (solution)

Quantity Value Units Method Reference Comment
Δr107. ± 13.kJ/molPACJohnson, Popov, et al., 1991solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation.

Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Hydrogen (solution) = C8H7O3V (solution) + Carbon monoxide (solution)

By formula: C9H5O4V (solution) + H2 (solution) = C8H7O3V (solution) + CO (solution)

Quantity Value Units Method Reference Comment
Δr56. ± 5.kJ/molPACJohnson, Popov, et al., 1991solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation.

Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Nitrogen (solution) = C8H5N2O3V (solution) + Carbon monoxide (solution)

By formula: C9H5O4V (solution) + N2 (solution) = C8H5N2O3V (solution) + CO (solution)

Quantity Value Units Method Reference Comment
Δr27. ± 4.kJ/molPACJohnson, Popov, et al., 1991solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation.

Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Carbon monoxide (solution) = Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Carbon monoxide (solution)

By formula: C9H5O4V (solution) + CO (solution) = C9H5O4V (solution) + CO (solution)

Quantity Value Units Method Reference Comment
Δr0. ± 1.kJ/molPACJohnson, Popov, et al., 1991solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Johnson, Popov, et al., 1991
Johnson, F.P.A.; Popov, V.K.; George, M.W.; Bagratashvili, V.N.; Poliakoff, M.; Turner, J.J., Mendeleev Commun., 1991, 145.. [all data]


Notes

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