Ferrocene, formyl-
- Formula: C11H10FeO
- Molecular weight: 214.042
- IUPAC Standard InChI: InChI=1S/C6H5O.C5H5.Fe/c7-5-6-3-1-2-4-6;1-2-4-5-3-1;/h1-5H;1-5H;
- IUPAC Standard InChIKey: UQTCQJVPLIVCAX-UHFFFAOYSA-N
- CAS Registry Number: 12093-10-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Ferrocenecarboxaldehyde; Ferrocenealdehyde; Ferrocenecarbaldehyde; Formyldicyclopentadienyliron; Formylferrocene; Iron, π-cyclopentadienyl(formyl-π-cyclopentadienyl)-; Ferrocenaldehyde; Ferrocene carboxyaldehyde; 2-Ferrocenecarboxaldehyde; Cyclopentadienecarboxaldehyde, cyclopentadienyliron deriv.; Ferrocenylcarboxaldehyde; NSC 407052; Ferrocenecarboxaldehdye
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Options:
Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 89.7 ± 5.1 | kJ/mol | ME | Lousada, Pinto, et al., 2008 | |
| ΔsubH° | 87.9 ± 3.5 | kJ/mol | ME | Lousada, Pinto, et al., 2008 |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 89.9 ± 5.1 | 305. | ME | Lousada, Pinto, et al., 2008 | Based on data from 302. to 312. K. |
| 87.3 ± 3.5 | 310. | ME | Lousada, Pinto, et al., 2008 | Based on data from 302. to 312. K. |
Enthalpy of fusion
| ΔfusH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 2.5 | 397.2 | DSC | Lousada, Pinto, et al., 2008 | |
| 2.76 | 397.6 | AC | Kaneko and Sorai, 2007 | Based on data from 13. to 405. K. |
| 2.05 | 396.7 | N/A | Daniel, Leadbetter, et al., 1978 |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lousada, Pinto, et al., 2008
Lousada, Cláudio M.; Pinto, Susana S.; Canongia Lopes, José N.; Minas da Piedade, M. Fátima; Diogo, Hermínio P.; Minas da Piedade, Manuel E.,
Experimental and Molecular Dynamics Simulation Study of the Sublimation and Vaporization Energetics of Iron Metalocenes. Crystal Structures of Fe(η 5 -C 5 H 4 CH 3 ) 2 and Fe[(η 5 -(C 5 H 5 )(η 5 -C 5 H 4 CHO)],
J. Phys. Chem. A, 2008, 112, 13, 2977-2987, https://doi.org/10.1021/jp7107818
. [all data]
Kaneko and Sorai, 2007
Kaneko, Y.; Sorai, M.,
Heat capacity and phase transitions of the plastic crystal formylferrocene,
Phase Transitions, 2007, 80, 6-7, 517-528, https://doi.org/10.1080/01411590701339401
. [all data]
Daniel, Leadbetter, et al., 1978
Daniel, M.F.; Leadbetter, Alan J.; Meads, R.E.; Parker, W.G.,
Structure of the ferrocene carboxaldehyde mesophase by X-ray diffraction and M«65533»ssbauer spectroscopy,
J. Chem. Soc., Faraday Trans. 2, 1978, 74, 456, https://doi.org/10.1039/f29787400456
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.