Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-113.2 ± 1.3kcal/molReviewMartinho Simões 
Δfgas-117.2 ± 2.2kcal/molReviewMartinho Simões 
Δfgas-102. ± 0.7kcal/molReviewMartinho Simões 
Δfgas-115.2 ± 2.2kcal/molReviewMartinho SimõesSelected data. Average of the values from Evstigneeva and Shmyreva, 1965 and Lautsch, Erzberger, et al., 1958

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-125.7 ± 1.1kcal/molReviewMartinho SimõesMS
Δfsolid-129.7 ± 2.0kcal/molReviewMartinho SimõesMS
Δfsolid-127.7 ± 2.0kcal/molReviewMartinho SimõesSelected data. Average of the values from Evstigneeva and Shmyreva, 1965 and Lautsch, Erzberger, et al., 1958; MS
Δfsolid-114. ± 0.2kcal/molCC-SBChipperfield, Sneyd, et al., 1979Value corrected based on a set of ancillary data by J.A. Martinho Simões; The value for the enthalpy of combustion is not reported in Chipperfield, Sneyd, et al., 1979; MS
Quantity Value Units Method Reference Comment
Δcsolid-922.1 ± 1.0kcal/molCC-SBEvstigneeva and Shmyreva, 1965Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.; MS
Δcsolid-918.1 ± 2.0kcal/molCC-SBLautsch, Tröber, et al., 1963Please also see Lautsch, Erzberger, et al., 1958, Pedley and Rylance, 1977, and Cox and Pilcher, 1970.; MS
Quantity Value Units Method Reference Comment
solid,1 bar61.986cal/mol*KN/AChhor, Pommier, et al., 1983DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
51.336298.15Chhor, Pommier, et al., 1983T = 10 to 300 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

Manganese, tricarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Heptane (solution) = C14H21MnO2 (solution) + Carbon monoxide (solution)

By formula: C8H5MnO3 (solution) + C7H16 (solution) = C14H21MnO2 (solution) + CO (solution)

Quantity Value Units Method Reference Comment
Δr47. ± 2.kcal/molAVGN/AAverage of 18 values; Individual data points

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Evstigneeva and Shmyreva, 1965
Evstigneeva, E.V.; Shmyreva, G.O., Russ. J. Phys. Chem., 1965, 39, 529. [all data]

Lautsch, Erzberger, et al., 1958
Lautsch, W.F.; Erzberger, P.; Tröber, A., Wiss. Z. Tech. Hochsch. Chem. Leuna-Merseburg, 1958, 1, 31. [all data]

Chipperfield, Sneyd, et al., 1979
Chipperfield, J.R.; Sneyd, J.C.R.; Webster, D.E., J. Organometal. Chem., 1979, 178, 177. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Chhor, Pommier, et al., 1983
Chhor, K.; Pommier, C.; Diot, M., Low-temperature thermodynamic study of cymantrene (C5H5Mn(CO)3) and azacymantrene (C4H4NMn(CO)3), Mol. Cryst. Liq. Cryst., 1983, 100, 193-209. [all data]


Notes

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