magnesium sulphide


Solid Phase Heat Capacity (Shomate Equation)

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) 298. to 3000.
A 11.61570
B 0.880849
C 0.005112
D 0.003601
E -0.088246
F -86.43131
G 25.31900
H -82.63009
ReferenceChase, 1998
Comment Data last reviewed in September, 1977
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
298.10.8912.0212.03-0.00
300.10.9012.0912.030.02
400.11.4215.3012.461.14
500.11.7017.8913.302.29
600.11.9020.0414.253.47
700.12.0621.8815.214.67
800.12.1923.5016.155.88
900.12.3124.9517.057.11
1000.12.4226.2517.908.35
1100.12.5227.4418.729.59
1200.12.6328.5319.4910.85
1300.12.7329.5420.2212.12
1400.12.8230.4920.9213.40
1500.12.9231.3821.5914.68
1600.13.0232.2222.2315.98
1700.13.1233.0122.8417.29
1800.13.2133.7623.4318.60
1900.13.3134.4823.9919.93
2000.13.4035.1624.5321.26
2100.13.5035.8225.0522.61
2200.13.6036.4525.5623.96
2300.13.7037.0626.0425.33
2400.13.7937.6426.5126.70
2500.13.8938.2126.9728.09
2600.13.9938.7527.4129.48
2700.14.0939.2827.8430.89
2800.14.1939.8028.2632.30
2900.14.2940.3028.6733.72
3000.14.3940.7829.0635.16

References

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), References