Al2H6 radical


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen anion + H6Al2 = H7Al2-

By formula: H- + H6Al2 = H7Al2-

Quantity Value Units Method Reference Comment
Δr322. ± 17.kJ/molCIDTGoebbert, Hernandez, et al., 2005gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.40 ± 0.10LPESZhang, Wang, et al., 2013Stated electron affinity is the Vertical Detachment Energy
2.40 ± 0.15LPESRao, Jena, et al., 2001EA is Vertical Detachment Energy, much larger than calculated adiabatic EA

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Hydrogen anion + H6Al2 = H7Al2-

By formula: H- + H6Al2 = H7Al2-

Quantity Value Units Method Reference Comment
Δr322. ± 17.kJ/molCIDTGoebbert, Hernandez, et al., 2005gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Goebbert, Hernandez, et al., 2005
Goebbert, D.J.; Hernandez, H.; Francisco, J.S.; Wenthold, P.G., The binding energy and bonding in dialane, J. Am. Chem. Soc., 2005, 127, 33, 11684-11689, https://doi.org/10.1021/ja0424070 . [all data]

Zhang, Wang, et al., 2013
Zhang, X.X.; Wang, H.P.; Collins, E.; Lim, A.; Gantefor, G.; Kiran, B.; Schnockel, H.; Eichhorn, B.; Bowen, K., Photoelectron spectroscopy of the aluminum hydride anions: AlH2-, AlH3-, Al2H6-, Al3H9-, and Al4H12-, J. Chem. Phys., 2013, 138, 12, 124303, https://doi.org/10.1063/1.4796200 . [all data]

Rao, Jena, et al., 2001
Rao, B.K.; Jena, P.; Burkart, S.; Gantefor, G.; Seifert, G., AlH3 and Al2H6: Magic clusters with unmagical properties, Phys. Rev. Lett., 2001, 86, 4, 692-695, https://doi.org/10.1103/PhysRevLett.86.692 . [all data]


Notes

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