Al2H6 radical


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

Hydrogen anion + H6Al2 = H7Al2-

By formula: H- + H6Al2 = H7Al2-

Quantity Value Units Method Reference Comment
Δr322. ± 17.kJ/molCIDTGoebbert, Hernandez, et al., 2005gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.40 ± 0.10LPESZhang, Wang, et al., 2013Stated electron affinity is the Vertical Detachment Energy
2.40 ± 0.15LPESRao, Jena, et al., 2001EA is Vertical Detachment Energy, much larger than calculated adiabatic EA

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Goebbert, Hernandez, et al., 2005
Goebbert, D.J.; Hernandez, H.; Francisco, J.S.; Wenthold, P.G., The binding energy and bonding in dialane, J. Am. Chem. Soc., 2005, 127, 33, 11684-11689, https://doi.org/10.1021/ja0424070 . [all data]

Zhang, Wang, et al., 2013
Zhang, X.X.; Wang, H.P.; Collins, E.; Lim, A.; Gantefor, G.; Kiran, B.; Schnockel, H.; Eichhorn, B.; Bowen, K., Photoelectron spectroscopy of the aluminum hydride anions: AlH2-, AlH3-, Al2H6-, Al3H9-, and Al4H12-, J. Chem. Phys., 2013, 138, 12, 124303, https://doi.org/10.1063/1.4796200 . [all data]

Rao, Jena, et al., 2001
Rao, B.K.; Jena, P.; Burkart, S.; Gantefor, G.; Seifert, G., AlH3 and Al2H6: Magic clusters with unmagical properties, Phys. Rev. Lett., 2001, 86, 4, 692-695, https://doi.org/10.1103/PhysRevLett.86.692 . [all data]


Notes

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