Tetra-tert-butoxy titanium
- Formula: C16H36O4Ti
- Molecular weight: 340.322
- CAS Registry Number: 119279-48-0
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔvapH° | 66.1 ± 3.3 | kJ/mol | SG | Bradley and Swanwick, 1958 | See also Bradley and Hillyer, 1966. |
Enthalpy of vaporization
| ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 55.9 | 401. | A | Stephenson and Malanowski, 1987 | Based on data from 386. to 486. K. |
| 62.6 | 337. | SG | Bradley and Swanwick, 1958 | Based on data from 322. to 388. K. See also Boublik, Fried, et al., 1984. |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bradley and Swanwick, 1958
Bradley, D.C.; Swanwick, J.D.,
650. Vapour pressures of metal alkoxides. Part I. Titanium tetra-tert.-butoxide and -amyloxide,
J. Chem. Soc., 1958, 3207, https://doi.org/10.1039/jr9580003207
. [all data]
Bradley and Hillyer, 1966
Bradley, D.C.; Hillyer, M.J.,
Thermochemistry of metal alkoxides. Part 2.?Heats of formation of some titanium alkoxides,
Trans. Faraday Soc., 1966, 62, 2374, https://doi.org/10.1039/tf9666202374
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E.,
The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]
Notes
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- Symbols used in this document:
ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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