Trimethyl methanetricarboxylate

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-252.08 ± 0.36kcal/molCcbRakus, Verevkin, et al., 1995 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-274.21 ± 0.31kcal/molCcbRakus, Verevkin, et al., 1995 
Quantity Value Units Method Reference Comment
Δcsolid-725.72 ± 0.31kcal/molCcbRakus, Verevkin, et al., 1995Corresponding Δfsolid = -274.21 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil515.9KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Δsub22.1 ± 0.2kcal/molVRakus, Verevkin, et al., 1995ALS
Δsub22.1kcal/molN/ARakus, Verevkin, et al., 1995DRB

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
401.20.020Weast and Grasselli, 1989BS

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rakus, Verevkin, et al., 1995
Rakus, K.; Verevkin, S.P.; Keller, M.; Beckhaus, H.-D.; Ruchardt, C., Radical stabilization enthalpies of α,α-bis(methoxycarbonyl)alkyl and tris(methoxycarbonyl)methyl radicals, Liebigs Ann. Chem., 1995, 1483-1493. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]


Notes

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