Difluorodinitromethane


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-403. ± 6.7kJ/molCcbPepekin, Lebedev, et al., 1973hf_HF.30H2O=-77.01 kcal/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-444.8 ± 6.7kJ/molCcbPepekin, Lebedev, et al., 1973hf_HF.30H2O=-77.01 kcal/mol
Quantity Value Units Method Reference Comment
Δcliquid-307. ± 5.9kJ/molCcbPepekin, Lebedev, et al., 1973hf_HF.30H2O=-77.01 kcal/mol

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap41. ± 0.8kJ/molVPepekin, Lebedev, et al., 1973hf_HF.30H2O=-77.01 kcal/mol; ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
41.4296.AStephenson and Malanowski, 1987Based on data from 283. to 310. K. See also Pepekin, Lebedev, et al., 1973, 2.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pepekin, Lebedev, et al., 1973
Pepekin, V.I.; Lebedev, Yu.A.; Apin, A.Ya., Dissociation energies of C-F and C-C bonds in α-fluoronitro derivatives of methane and ethane, Dokl. Akad. Nauk SSSR, 1973, 208, 153-155. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Pepekin, Lebedev, et al., 1973, 2
Pepekin, V.I.; Lebedev, Y.A.; Apin, A.Y., Dokl. Phys. Chem., 1973, 208, 35. [all data]


Notes

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