Ethene, tetrafluoro-
- Formula: C2F4
- Molecular weight: 100.0150
- IUPAC Standard InChIKey: BFKJFAAPBSQJPD-UHFFFAOYSA-N
- CAS Registry Number: 116-14-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Ethylene, tetrafluoro-; Perfluoroethene; Perfluoroethylene; Tetrafluoroethene; Tetrafluoroethylene; TFE; C2F4; Fluoroplast 4; Tetrafluorethylene; 1,1,2,2-Tetrafluoroethylene; Tetrafluorethene; Ethene, 1,1,2,2-tetrafluoro-
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 196.8 | K | N/A | PCR Inc., 1990 | BS |
Tboil | 199. | K | N/A | Lazerte, Hals, et al., 1953 | Uncertainty assigned by TRC = 3. K; TRC |
Tboil | 196.7 | K | N/A | Ruff and Bretschneider, 1933 | Uncertainty assigned by TRC = 0.5 K; not clear whether directly measured or extrapolated; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 130.65 | K | N/A | Ruff and Bretschneider, 1933 | Uncertainty assigned by TRC = 0.5 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 142.00 | K | N/A | Furukawa, McCoskey, et al., 1953 | Uncertainty assigned by TRC = 0.02 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 307.4 | K | N/A | Lebedeva and Khodeeva, 1967 | TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 5.842 | mol/l | N/A | Lebedeva and Khodeeva, 1967 | Method as Lebedeva and Khodeeva Russ.J.Phys.Chem. 1961,35,1 sample stabilised with trimethylamine; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
16.821 | 197.53 | N/A | Furukawa, McCoskey, et al., 1953 | P = 101.325 kPa; DH |
16.8 | 258. | A | Stephenson and Malanowski, 1987 | Based on data from 197. to 273. K.; AC |
16.6 | 288. | A | Stephenson and Malanowski, 1987 | Based on data from 273. to 306. K.; AC |
18.6 | 193. | A | Stephenson and Malanowski, 1987 | Based on data from 142. to 208. K. See also Furukawa, Mccoskey, et al., 1953 and Boublik, Fried, et al., 1984.; AC |
Entropy of vaporization
ΔvapS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
85.16 | 197.53 | Furukawa, McCoskey, et al., 1953 | P; DH |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
141.99 to 208.40 | 4.02877 | 686.188 | -26.945 | Furukawa, McCoskey, et al., 1953 | Coefficents calculated by NIST from author's data. |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
7.7145 | 142.00 | Furukawa, McCoskey, et al., 1953 | DH |
7.71 | 142. | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
54.33 | 142.00 | Furukawa, McCoskey, et al., 1953 | DH |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
PCR Inc., 1990
PCR Inc.,
Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]
Lazerte, Hals, et al., 1953
Lazerte, J.D.; Hals, L.J.; Ried, T.S.; Smith, G.H.,
Pyrolyses of the Salts of the Perfluoro Carboxylic Acids,
J. Am. Chem. Soc., 1953, 75, 4525. [all data]
Ruff and Bretschneider, 1933
Ruff, O.; Bretschneider, O.,
The Preparation of Hexafluoroethane and Tetrafluoroethene from Tetrafluoromethane,
Z. Anorg. Allg. Chem., 1933, 210, 173. [all data]
Furukawa, McCoskey, et al., 1953
Furukawa, G.T.; McCoskey, R.E.; Reilly, M.L.,
Heat capacity, heats of fusion and vaporization, and vapor pressure of tetrafluoroethylene,
J. Res., 1953, NBS 51, 69-72. [all data]
Lebedeva and Khodeeva, 1967
Lebedeva, E.S.; Khodeeva, S.M.,
Liquid-Liquid-Gas Equilibrium in the System Tetrafluoroethylene-methanol,
Zh. Fiz. Khim., 1967, 41, 2081-3. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Furukawa, Mccoskey, et al., 1953
Furukawa, G.T.; Mccoskey, R.E.; Reilly, M.L.,
Heat capacity, heats of fusion and vaporization, and vapor pressure of tetrafluoroethylene,
J. RES. NATL. BUR. STAN., 1953, 51, 2, 69, https://doi.org/10.6028/jres.051.007
. [all data]
Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E.,
The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔvapH Enthalpy of vaporization ΔvapS Entropy of vaporization ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.