c70-Fullerene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δsub199. ± 2.kJ/molMESchonherr, Matsumoto, et al., 2000Based on data from 864. - 1099. K.; AC
Δsub200. ± 6.kJ/molVPiacente, Gigli, et al., 1996ALS
Δsub200. ± 6.0kJ/molN/APiacente, Gigli, et al., 1996AC

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
189.8 ± 3.1844.MEPiacente, Gigli, et al., 1996Based on data from 783. - 904. K.; AC
174. ± 3.0740.MEPopovic, Drazic, et al., 1994AC
193.4 ± 1.5750.MSSai Baba, Lakshmi Narasimhan, et al., 1994AC
186.6788.MEMathews, Baba, et al., 1993AC
188.3 ± 4.2673. - 873.MEAbrefah, Olander, et al., 1992AC
190. ± 4.673.VAbrefah, Olander, et al., 1992, 2crystal phase; High level of uncertainty in the data; ALS
196. ± 7.737.VMathews, Vasudeva Rao, et al., 1991ALS
180. ± 9.2739.VPan, Sampson, et al., 1991ALS
180.0 ± 9.2739.ME,MSPan, Sampson, et al., 1991Based on data from 640. - 800. K.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schonherr, Matsumoto, et al., 2000
Schonherr, E.; Matsumoto, K.; Murakami, K., Proc.-Electrochem. Soc., 2000, 12, 89. [all data]

Piacente, Gigli, et al., 1996
Piacente, V.; Gigli, G.; Scardala, P.; Giustini, A.; Bardi, G., Vapor pressure of C70 fullerene, J. Phys. Chem., 1996, 100, 9815-9819. [all data]

Popovic, Drazic, et al., 1994
Popovic, Arkadij; Drazic, Goran; Marsel, Joze, Mass spectrometric investigations of fullerenes. I. Vapour pressure over the C60/C70 binary system, Rapid Commun. Mass Spectrom., 1994, 8, 12, 985-990, https://doi.org/10.1002/rcm.1290081216 . [all data]

Sai Baba, Lakshmi Narasimhan, et al., 1994
Sai Baba, M.; Lakshmi Narasimhan, T.S.; Balasubramanian, R.; Sivaraman, N.; Mathews, C.K., Studies on the thermodynamics of the fullerene C60-C70 binary system, J. Phys. Chem., 1994, 98, 4, 1333-1340, https://doi.org/10.1021/j100055a047 . [all data]

Mathews, Baba, et al., 1993
Mathews, C.K.; Baba, M. Sai; Lakshmi Narasimhan, T.S.; Balasubramanian, R.; Sivaraman, N.; Srinivasan, T.G.; Vasudeva Rao, P.R., Vapour Pressure and Enthalpy of Sublimation of C 70, Fullerene Science and Technology, 1993, 1, 1, 101-109, https://doi.org/10.1080/15363839308015519 . [all data]

Abrefah, Olander, et al., 1992
Abrefah, J.; Olander, D.R.; Balooch, M.; Siekhaus, W.J., Vapor pressure of Buckminsterfullerene, Appl. Phys. Lett., 1992, 60, 11, 1313, https://doi.org/10.1063/1.107327 . [all data]

Abrefah, Olander, et al., 1992, 2
Abrefah, J.; Olander, D.R.; Balooch, M.; Siekhaus, W.J., Vapor pressure of buckminsterfullerene, Appl. Phys. Lett., 1992, 60, 1313-1314. [all data]

Mathews, Vasudeva Rao, et al., 1991
Mathews, C.K.; Vasudeva Rao, P.R.; Srinivasan, T.G.; Ganesan, V.; Sivaraman, N.; Lakshmi Narasimhan, T.S.L.; Kaliappan, I.; Chandran, K.; Dhamodaran, R., Preparation and characterization of buckministerfullerene and measurement of its heat of sublimation, Curr. Sci., 1991, 61, 834-838. [all data]

Pan, Sampson, et al., 1991
Pan, C.; Sampson, M.P.; Chai, Y.; Hauge, R.H.; Margrave, J.L., Heats of sublimation from a polycrystalline mixture of C60 and C70, J. Phys. Chem., 1991, 95, 2944-2946. [all data]


Notes

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