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1-Tetradecanol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-628.2 ± 1.5kJ/molCcrSteele, Chirico, et al., 1991«DELTA»Hfusion = 48.5±1.0 kcal/mol; ALS
Deltafsolid-629.6 ± 0.6kJ/molCcbMosselman and Dekker, 1975Hfusion =48.22±0.42; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-9168.4 ± 1.2kJ/molCcrSteele, Chirico, et al., 1991«DELTA»Hfusion = 48.5±1.0 kcal/mol; Corresponding «DELTA»fsolid = -628.18 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-9213. ± 8.kJ/molCcbFreeman and Bagby, 1989Corresponding «DELTA»fsolid = -582. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacsolid-9167.0 ± 0.6kJ/molCcbMosselman and Dekker, 1975Hfusion =48.22±0.42; Corresponding «DELTA»fsolid = -629.6 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
516.0313.15Khasanshin and Zykova, 1989T = 313 to 563 K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
426.5298.15N/AT = 274 to 564 K. C/R(c) = 0.360T - 56.06 (269 to 311 K); C/R(liq) = 0.159T + 13.618 (311 to 379 K), R = 8.31451 J/mol*K.; DH
388.298.15Mosselman, Mourik, et al., 1974«alpha»-form, 386 to 303 K.; DH
506.312.Mosselman, Mourik, et al., 1974T = 312 to 346 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1991
Steele, W.V.; Chirico, R.D.; Nguyen, A.; Hossenlopp, I.A.; Smith, N.K., DIPPR PROJECT 871: Determination of ideal-gas enthalpies of formation for key compounds: The 1989 project results, J. Chem. Thermodyn., 1991, 101-134. [all data]

Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H., Enthalpies of formation of n-alkan-1-ols, J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]

Freeman and Bagby, 1989
Freeman, B.; Bagby, M.O., Heats of combustion of fatty esters and triglycerides, J. Am. Oil Chem. Soc., 1989, 66, 1601-1605. [all data]

Khasanshin and Zykova, 1989
Khasanshin, T.S.; Zykova, T.B., Specific heat of saturated monatomic alcohols, Inzh. -Fiz. Zhur., 1989, 56(6), 991-994. [all data]

Mosselman, Mourik, et al., 1974
Mosselman, C.; Mourik, J.; Dekker, H., Enthalpies of phase change and heat capacities of some long-chain alcohols. Adiabatic semi-microcalorimeter for studies of polymorphism, J. Chem. Thermodynam., 1974, 6, 477-487. [all data]


Notes

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