1-Tetradecanol
- Formula: C14H30O
- Molecular weight: 214.3874
- IUPAC Standard InChIKey: HLZKNKRTKFSKGZ-UHFFFAOYSA-N
- CAS Registry Number: 112-72-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Species with the same structure:
- Other names: n-Tetradecan-1-ol; n-Tetradecanol; n-Tetradecyl alcohol; Alfol 14; Lanette K; Lanette Wax KS; Loxanol V; Myristic alcohol; Myristyl alcohol; Tetradecyl alcohol; n-Tetradecanol-1; 1-Hydroxytetradecane; Dytol R-52; Tetradecanol; Dehydag wax 14; Epal 14; Lanette 14; Lorol C14; Philcohol 1400; Tetradecanol-1; Tetradecan-1-ol; NSC 8549; Fatty alcohol (C14); 150138-88-8; 8032-14-2
- Information on this page:
- Other data available:
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Gas phase thermochemistry data
Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -113.5 ± 0.62 | kcal/mol | Ccr | Steele, Chirico, et al., 1991 | ΔHfusion = 48.5±1.0 kcal/mol; ALS |
ΔfH°gas | -113.8 | kcal/mol | N/A | Mosselman and Dekker, 1975 | Value computed using ΔfHsolid° value of -629.6±0.6 kj/mol from Mosselman and Dekker, 1975 and ΔsubH° value of 153.4 kj/mol from Steele, Chirico, et al., 1991.; DRB |
Phase change data
Go To: Top, Gas phase thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 562.2 | K | N/A | Aldrich Chemical Company Inc., 1990 | BS |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 311. ± 1. | K | AVG | N/A | Average of 11 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 311.35 | K | N/A | Spizzichino, 1956 | Uncertainty assigned by TRC = 0.5 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 24.43 | kcal/mol | N/A | Majer and Svoboda, 1985 | |
ΔvapH° | 23.6 ± 0.60 | kcal/mol | CGC | Nichols, Kweskin, et al., 2006 | AC |
ΔvapH° | 23.6 | kcal/mol | GS | Kulikov, Verevkin, et al., 2001 | Based on data from 312. to 346. K.; AC |
ΔvapH° | 24.43 ± 0.55 | kcal/mol | C | Månsson, Sellers, et al., 1977 | AC |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 36.66 ± 0.45 | kcal/mol | V | Steele, Chirico, et al., 1991 | ΔHfusion = 48.5±1.0 kcal/mol; ALS |
ΔsubH° | 36.66 | kcal/mol | N/A | Steele, Chirico, et al., 1991 | DRB |
ΔsubH° | 24.43 ± 0.55 | kcal/mol | C | Mansson, Sellers, et al., 1977 | ALS |
ΔsubH° | 34.4 ± 0.5 | kcal/mol | V | Davies and Kybett, 1965 | ALS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
22.4 | 328. | GS | Kulikov, Verevkin, et al., 2001 | Based on data from 312. to 346. K.; AC |
19.6 | 386. | N/A | N'Guimbi, Kasehgari, et al., 1992 | Based on data from 333. to 438. K.; AC |
26.1 | 332. | A | Stephenson and Malanowski, 1987 | Based on data from 317. to 358. K.; AC |
18.3 | 439. | A | Stephenson and Malanowski, 1987 | Based on data from 424. to 569. K. See also Kemme and Kreps, 1969.; AC |
25.43 | 328. | N/A | Wilhoit and Zwolinski, 1973 | Based on data from 313. to 358. K.; AC |
24.90 | 320. | ME | Davies and Kybett, 1965 | Based on data from 313. to 326. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference |
---|---|---|---|---|
424.8 to 569.1 | 3.60326 | 1412.907 | -177.782 | Kemme and Kreps, 1969 |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
34.39 | 300. | ME | Davies and Kybett, 1965 | Based on data from 293. to 307. K.; AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
11.807 | 311. | N/A | N/A | DH |
11.30 | 308.1 | DSC | Zeng, Cao, et al., 2009 | AC |
Entropy of fusion
ΔfusS (cal/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
36.099 | 311.2 | Mosselman and Mouric, 1974 | CAL |
19.30 | 310.8 | ||
1.40 | 306. | ||
18.30 | 311. | ||
16.90 | 311.6 | ||
37.942 | 311. |
Enthalpy of phase transition
ΔHtrs (kcal/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
0.4302 | 306. | crystaline, β | crystaline, | Mosselman, Mourik, et al., 1974 | DH |
5.6883 | 311.2 | crystaline, β | crystaline, α | Mosselman, Mourik, et al., 1974 | DH |
11.833 | 311.0 | crystaline, β | liquid | Mosselman, Mourik, et al., 1974 | DH |
5.9990 | 310.8 | crystaline, α | liquid | Mosselman, Mourik, et al., 1974 | DH |
Entropy of phase transition
ΔStrs (cal/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
1.4 | 306. | crystaline, β | crystaline, | Mosselman, Mourik, et al., 1974 | DH |
18.3 | 311.2 | crystaline, β | crystaline, α | Mosselman, Mourik, et al., 1974 | DH |
38.05 | 311.0 | crystaline, β | liquid | Mosselman, Mourik, et al., 1974 | DH |
Mass spectrum (electron ionization)
Go To: Top, Gas phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 22632 |
Gas Chromatography
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | DB-5 | 170. | 1675. | Svatoz, Kalinová, et al., 1999 | 30. m/0.25 mm/0.25 μm |
Packed | OV-101 | 220. | 1664.4 | Didaoui, Touabet, et al., 1997 | N2, Chromosorb G HP; Column length: 2. m |
Capillary | SE-30 | 200. | 1678.2 | Didaoui, Touabet, et al., 1997 | 27. m/0.4 mm/0.1 μm, N2, Chromosorb G HP |
Capillary | CP Sil 5 CB | 240. | 1676. | Hanai and Hong, 1989 | 30. m/0.25 mm/0.25 μm |
Capillary | DB-1 | 240. | 1669. | Hanai and Hong, 1989 | 30. m/0.25 mm/0.25 μm |
Capillary | SE-30 | 120. | 1646. | Haken and Korhonen, 1985 | Column length: 25. m; Column diameter: 0.33 mm |
Capillary | SE-30 | 140. | 1652. | Haken and Korhonen, 1985 | Column length: 25. m; Column diameter: 0.33 mm |
Capillary | SE-30 | 160. | 1655. | Haken and Korhonen, 1985 | Column length: 25. m; Column diameter: 0.33 mm |
Capillary | SE-30 | 180. | 1657. | Haken and Korhonen, 1985 | Column length: 25. m; Column diameter: 0.33 mm |
Capillary | SE-30 | 200. | 1659. | Haken and Korhonen, 1985 | Column length: 25. m; Column diameter: 0.33 mm |
Capillary | SE-30 | 220. | 1653. | Haken and Korhonen, 1985 | Column length: 25. m; Column diameter: 0.33 mm |
Capillary | SE-30 | 240. | 1661. | Haken and Korhonen, 1985 | Column length: 25. m; Column diameter: 0.33 mm |
Capillary | SE-30 | 260. | 1670. | Haken and Korhonen, 1985 | Column length: 25. m; Column diameter: 0.33 mm |
Packed | Apiezon L | 190. | 1658. | Nedopekina, Kovalev, et al., 1981 | N2, Chromatron N-AW-HMDS; Column length: 2.5 m |
Packed | SE-30 | 180. | 1669. | Zarazir, Chovin, et al., 1970 | Chromosorb W; Column length: 2. m |
Kovats' RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | CP Sil 8 CB | 1664. | Schwob, Bessiere, et al., 2004 | 30. m/0.25 mm/0.25 μm, H2, 50. C @ 2. min, 3. K/min; Tend: 220. C |
Capillary | PTE-5 | 1680. | Gudzic, Dordevic, et al., 2001 | 60. m/0.32 mm/0.39 μm, H2, 4.3 K/min; Tstart: 60. C; Tend: 285. C |
Capillary | OV-101 | 1675. | Ohnishi and Shibamoto, 1984 | 2. K/min; Column length: 50. m; Column diameter: 0.23 mm; Tstart: 80. C; Tend: 200. C |
Capillary | OV-101 | 1680. | Ohnishi and Shibamoto, 1984 | 2. K/min; Column length: 50. m; Column diameter: 0.23 mm; Tstart: 80. C; Tend: 200. C |
Kovats' RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | CP Sil 8 CB | 1673. | Radusiene, Judzentiene, et al., 2005 | 50. m/0.32 mm/0.25 μm, He; Program: 60C(1min) => 3C/min => 70C => 15C/min => 170C(8min) => 5C/min => 250C |
Kovats' RI, polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Capillary | CP-Wax | 240. | 2137. | Hanai and Hong, 1989 | 25. m/0.25 mm/0.22 μm |
Capillary | DB-Wax | 240. | 2175. | Hanai and Hong, 1989 | 25. m/0.25 mm/0.22 μm |
Capillary | OV-351 | 140. | 2164. | Haken and Korhonen, 1985 | N2; Column length: 25. m; Column diameter: 0.32 mm |
Capillary | OV-351 | 160. | 2161. | Haken and Korhonen, 1985 | N2; Column length: 25. m; Column diameter: 0.32 mm |
Capillary | OV-351 | 180. | 2165. | Haken and Korhonen, 1985 | N2; Column length: 25. m; Column diameter: 0.32 mm |
Capillary | OV-351 | 200. | 2165. | Haken and Korhonen, 1985 | N2; Column length: 25. m; Column diameter: 0.32 mm |
Capillary | OV-351 | 220. | 2177. | Haken and Korhonen, 1985 | N2; Column length: 25. m; Column diameter: 0.32 mm |
Capillary | Carbowax 20M | 130. | 2170. | Hedin, Thopson, et al., 1972 | N2; Column length: 15.24 m; Column diameter: 0.5 mm |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | VF-5MS | 1679. | Todua, 2011 | 30. m/0.25 mm/0.25 μm, He; Tstart: 60. C; Tend: 270. C |
Capillary | Mega 5MS | 1674. | Condurso, Verzera, et al., 2006 | 60. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 60. C; Tend: 240. C |
Capillary | BPX-5 | 1686. | Dickschat J.S., Wagner-Dobler I., et al., 2005 | 25. m/0.25 mm/0.25 μm, He, 50. C @ 5. min, 5. K/min; Tend: 300. C |
Capillary | HP-5MS | 1676. | Demetzos, Angelopoulou, et al., 2002 | 30. m/0.25 mm/0.25 μm, 50. C @ 5. min, 3. K/min; Tend: 280. C |
Capillary | HP-5MS | 1676. | Demetzos, Angelopoulou, et al., 2002 | 30. m/0.25 mm/0.25 μm, 50. C @ 5. min, 3. K/min; Tend: 280. C |
Capillary | CP Sil 5 CB | 1675. | Heinrich, Pfeifhofer, et al., 2002 | 50. m/0.25 mm/0.15 μm, H2, 40. C @ 3. min, 4. K/min; Tend: 300. C |
Capillary | HP-5 | 1672. | Lazari, Skaltsa, et al., 2000 | 30. m/0.25 mm/0.25 μm, He, 50. C @ 5. min, 4. K/min; Tend: 280. C |
Capillary | CP Sil 5 CB | 1661. | Pfeifhofer, 2000 | 50. m/0.22 mm/0.13 μm, H2, 4. K/min, 300. C @ 10. min; Tstart: 40. C |
Capillary | DB-1 | 1647. | Peng, 1992 | 15. m/0.53 mm/1. μm, 40. C @ 4. min, 8. K/min; Tend: 250. C |
Capillary | DB-5 | 1676. | Rostad and Pereira, 1986 | 30. m/0.26 mm/0.25 μm, He, 50. C @ 4. min, 6. K/min, 300. C @ 20. min |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | HP-5MS | 1679. | Andriamaharavo, 2014 | 30. m/0.25 mm/0.25 μm, He; Program: 60C (1 min) => 5 C/min => 210C => 10 C/min => 280C (15 min) |
Capillary | VF-5MS | 1681.1 | Tret'yakov, 2007 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
Capillary | DB-1 | 1664. | Peng, 2000 | 15. m/0.53 mm/1. μm, He; Program: 40C(3min) => 8C/min => 200(1min) => 5C/min => 300C(25min) |
Capillary | SE-52 | 1675. | Mondello, Dugo, et al., 1995 | 60. m/0.32 mm/0.40 μm, He; Program: 45 C (6 min) 3 C/min -> 111 0C 2 C/min -> 160 C 3 C/min -> 300 C (15 min) |
Capillary | Methyl Silicone | 1647. | Peng, Yang, et al., 1991 | Program: not specified |
Packed | SE-30 | 1647. | Peng, Ding, et al., 1988 | Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min) |
Van Den Dool and Kratz RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-Wax | 2200. | Gurbuz O., Rouseff J.M., et al., 2006 | 60. m/0.25 mm/0.25 μm, He, 7. K/min, 265. C @ 5. min; Tstart: 40. C |
Capillary | ZB-Wax | 2123. | Brunton, Cronin, et al., 2002 | 60. m/0.32 mm/0.25 μm, He, 3. K/min; Tstart: 40. C; Tend: 220. C |
Capillary | DB-Wax | 2174. | Choi, Kim. M.-S.L., et al., 2002 | 60. m/0.25 mm/0.25 μm, N2, 2. K/min, 230. C @ 20. min; Tstart: 70. C |
Capillary | Carbowax 20M | 2155. | Mondello, Dugo, et al., 1995 | 60. m/0.32 mm/0.425 μm, He, 45. C @ 3. min, 3. K/min, 300. C @ 20. min |
Capillary | DB-Wax | 2204. | Shiratsuchi, Shimoda, et al., 1994 | 60. m/0.25 mm/0.25 μm, 2. K/min, 230. C @ 60. min; Tstart: 50. C |
Capillary | Supelcowax-10 | 2173. | Chung and Cadwallader, 1993 | 60. m/0.25 mm/0.25 μm, He, 40. C @ 5. min, 2. K/min, 195. C @ 40. min |
Capillary | Carbowax 20M | 2157. | Peng, 1992 | 8. K/min, 200. C @ 60. min; Column length: 3.05 m; Tstart: 40. C |
Packed | Carbowax 20M | 2157. | Peng, Yang, et al., 1991 | Supelcoport, 40. C @ 4. min, 8. K/min; Column length: 3.05 m; Tend: 200. C |
Capillary | Carbowax 20M | 2131. | Schwab, Mahr, et al., 1989 | 30. m/0.25 mm/0.25 μm, He, 40. C @ 3. min, 4. K/min; Tend: 240. C |
Van Den Dool and Kratz RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | CP-Wax 52CB | 2152. | Condurso, Verzera, et al., 2006 | 60. m/0.25 mm/0.25 μm, He; Program: 45C(5min) => 10C/min => 80C => 2C/min => 240C |
Capillary | DB-Wax | 2145. | Ferrari, Lablanquie, et al., 2004 | 60. m/0.25 mm/0.25 μm, He; Program: 35C(0.7min) => 20C/min => 70C => 4C/min => 240C |
Normal alkane RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | HP-5 | 1676. | Cavar, Maksimovic, et al., 2010 | 30. m/0.252 mm/0.25 μm, Helium, 3. K/min; Tstart: 60. C; Tend: 240. C |
Capillary | HP-5 MS | 1675. | Radulovic, Blagojevic, et al., 2010 | 30. m/0.25 mm/0.25 μm, Helium, 5. K/min, 290. C @ 10. min; Tstart: 70. C |
Capillary | DB-5 | 1670. | Smelcerovic, Spiteller, et al., 2007 | 30. m/0.25 mm/0.25 μm, He, 10. K/min, 320. C @ 4. min; Tstart: 60. C |
Capillary | BPX5 | 1687. | Dickschat, Bode, et al., 2005 | 25. m/0.22 mm/0.25 μm, Helium, 50. C @ 5. min, 5. K/min; Tend: 320. C |
Capillary | HP-5 | 1680.6 | Leffingwell and Alford, 2005 | 60. m/0.32 mm/0.25 μm, He, 30. C @ 2. min, 2. K/min, 260. C @ 28. min |
Capillary | SPB-1 | 1660. | Wong and Tan, 2005 | 50. m/0.2 mm/0.33 μm, He, 50. C @ 3. min, 4. K/min, 220. C @ 30. min |
Capillary | HP-5 | 1665. | N/A | 30. m/0.32 mm/0.25 μm, Helium, 40. C @ 2. min, 5. K/min, 250. C @ 5. min |
Capillary | HP-5 | 1676. | Velickovic, Randjelovic, et al., 2002 | 30. m/0.25 mm/0.25 μm, H2, 4. K/min; Tstart: 40. C; Tend: 280. C |
Capillary | DB-5 | 1680. | Palmeira, Conserva, et al., 2001 | 30. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 60. C; Tend: 270. C |
Capillary | Optima-1 | 1677. | de Beck, Bessière, et al., 2000 | 25. m/0.20 mm/0.25 μm, He, 50. C @ 3. min, 3. K/min; Tend: 250. C |
Capillary | SPB-5 | 1668. | Kim, Kim, et al., 2000 | 60. m/0.25 mm/0.25 μm, He, 70. C @ 8. min, 5. K/min, 240. C @ 20. min |
Capillary | DB-5 | 1652. | Reverchon, Porta, et al., 1997 | 30. m/0.25 mm/0.25 μm, He, 50. C @ 5. min, 2. K/min; Tend: 250. C |
Capillary | Ultra-1 | 1659. | Okumura, 1991 | 25. m/0.32 mm/0.25 μm, He, 3. K/min; Tstart: 80. C; Tend: 260. C |
Capillary | DB-1 | 1663. | Shiota, 1991 | 60. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 240. C |
Capillary | DB-1 | 1665. | Shiota, 1991 | 60. m/0.25 mm/0.25 μm, He, 3. K/min; Tstart: 50. C; Tend: 240. C |
Capillary | SE-30 | 1653. | Yaacob, Abdullah, et al., 1989 | 4. K/min; Column length: 10. m; Column diameter: 0.25 mm; Tstart: 20. C; Tend: 200. C |
Capillary | SE-54 | 1678. | Bestmann, Classen, et al., 1988 | N2, 60. C @ 2. min, 6. K/min; Column length: 25. m; Column diameter: 0.25 mm; Tend: 260. C |
Normal alkane RI, non-polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | TR-5 MS | 1685. | Kurashov, Mitrukova, et al., 2014 | 15. m/0.25 mm/0.25 μm, Helium; Program: 35 0C (3 min) 2 0C/min -> 60 0C (3 min) 2 0C/min -> 80 0C (3 min) 4 0C/min -> 120 0C (3 min) 5 0C/min -> 150 0C (3 min) 15 0C/min -> 240 0C (10 min) |
Capillary | SLB-5 MS | 1671. | Mondello, 2012 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
Capillary | SLB-5 MS | 1683. | Mondello, 2012 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
Capillary | Siloxane, 5 % Ph | 1692. | VOC BinBase, 2012 | Program: not specified |
Capillary | Polydimethyl siloxane, 5 % phenyl | 1692. | Skogerson, Wohlgemuth, et al., 2011 | Program: not specified |
Capillary | HP-5 MS | 1672. | Mancini, Arnold, et al., 2009 | 30. m/0.25 mm/0.25 μm, Helium; Program: 40 0C (5 min) 2 0C/min -> 270 0C -> 260 0C (20 min) |
Capillary | BPX-5 | 1684. | se Souza, Cardeal, et al., 2009 | 30. m/0.25 mm/0.25 μm, Helium; Program: 35 0C (5 min) 3 0C/min -> 210 0C 40 0C/min -> 240 0C (10 min) |
Capillary | BPX-5 | 1680. | se Souza, Cardeal, et al., 2009 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
Capillary | DB-5 | 1672. | Judzentiene and Budiene, 2008 | 50. m/0.32 mm/0.25 μm, Helium; Program: 60 0C (2 min) 5 0C/min -> 160 0C (1 min) 10 0C/min -> 250 0C (3 min) |
Capillary | DB-5 | 1673. | Nivinsliene, Butkiene, et al., 2007 | 50. m/0.32 mm/0.25 μm, Helium; Program: 60 0C (1 min) 5 0C/min -> 160 0C 10 0C/min -> 250 0C |
Capillary | HP-5 | 1677. | Demyttenaere, Sánchez Martínez, et al., 2003 | 30. m/0.25 mm/0.25 μm, He; Program: 35C => 5C/min => 220C => 10C/min => 240C(5min) |
Capillary | DB-5 | 1675. | Kalinová, Svatos, et al., 2003 | 30. m/0.25 mm/0.25 μm, He; Program: 70 0C (2 min) 4 K/min -> 140 0C 5 K/min -> 220 0C 20 K/min -> 280 0C (5 min) |
Capillary | BPX-5 | 1680. | Machiels, van Ruth, et al., 2003 | 60. m/0.32 mm/1. μm, He; Program: 40C (4min) => 2C/min => 90C => 4C/min => 130C => 8C/min => 250 C (10min) |
Capillary | CP-Sil 8CB-MS | 1676. | Mockute, Bernotiene, et al., 2003 | Column length: 50. m; Column diameter: 0.32 mm; Program: 60C(1min) => 3C/min => 70C => 15C/min => 170C(8min) => 5C/min => 250C |
Capillary | HP-5MS | 1677. | Demyttenaere, Sánchez Martínez, et al., 2002 | 30. m/0.25 mm/0.25 μm, He; Program: 35C => 5C/min => 160C => 10C/min => 220C (10min) |
Capillary | DB-5 | 1673. | Morteza-Semnani and Vahedi, 2002 | Program: not specified |
Capillary | BPX-5 | 1662. | Madruga, Arruda, et al., 2000 | 50. m/0.32 mm/0.50 μm, Helium; Program: 40 0C (5 min) 20 0C/min -> 60 0C (5 min) 4 0C/min -> 250 0C (10 min) |
Capillary | CP Sil 5 CB | 1665. | Weyerstahl, Marschall, et al., 1999 | Column length: 25. m; Column diameter: 0.39 mm; Program: not specified |
Normal alkane RI, polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | AT-Wax | 2180. | Kiss, Csoka, et al., 2011 | 60. m/0.25 mm/0.25 μm, Helium, 4. K/min; Tstart: 60. C; Tend: 280. C |
Capillary | ZB-Wax | 2169. | N/A | 30. m/0.32 mm/0.25 μm, Helium, 40. C @ 2. min, 5. K/min, 250. C @ 5. min |
Normal alkane RI, polar column, custom temperature program
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | Innowax FSC | 2179. | Akin, Saracoglu, et al., 2012 | 60. m/0.25 mm/0.25 μm, Helium; Program: 60 0C (10 min) 4 0C/min -> 220 0C (10 min) 1 oC/min -> 240 0C |
Capillary | Innowax FSC | 2179. | Bardakci, Demirci, et al., 2012 | 60. m/0.25 mm/0.25 μm, Helium; Program: 60 0C (10 min) 4 0C/min -> 220 0C 1 0C/min -> 240 0C |
Capillary | DB-Wax | 2152. | Welke, Manfroi, et al., 2012 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
Capillary | DB-Wax | 2172. | Welke, Manfroi, et al., 2012 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
Capillary | HP Innowax | 2175. | Mancini, Arnold, et al., 2009 | 50. m/0.20 mm/0.25 μm, Helium; Program: 40 0C (5 min) 2 0C/min -> 270 0C -> 260 0C (20 min) |
Capillary | DB-Wax | 2157. | Peng, Yang, et al., 1991, 2 | Program: not specified |
Lee's RI, non-polar column, temperature ramp
Column type | Active phase | I | Reference | Comment |
---|---|---|---|---|
Capillary | DB-5MS | 282.29 | Chen, Keeran, et al., 2002 | 30. m/0.25 mm/0.5 μm, 40. C @ 1. min, 10. K/min; Tend: 310. C |
Capillary | DB-5MS | 283.90 | Chen, Keeran, et al., 2002 | 30. m/0.25 mm/0.5 μm, 40. C @ 1. min, 4. K/min; Tend: 310. C |
Capillary | DB-5 | 283.29 | Rostad and Pereira, 1986 | 30. m/0.26 mm/0.25 μm, He, 50. C @ 4. min, 6. K/min, 300. C @ 20. min |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Notes
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- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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