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2,5,8,11-Tetraoxadodecane

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H10N+ + 2,5,8,11-Tetraoxadodecane = (C3H10N+ bullet 2,5,8,11-Tetraoxadodecane)

By formula: C3H10N+ + C8H18O4 = (C3H10N+ bullet C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar145.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Deltar167.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

C4H5N2+ + 2,5,8,11-Tetraoxadodecane = (C4H5N2+ bullet 2,5,8,11-Tetraoxadodecane)

By formula: C4H5N2+ + C8H18O4 = (C4H5N2+ bullet C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar155.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Deltar173.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

C6H14N+ + 2,5,8,11-Tetraoxadodecane = (C6H14N+ bullet 2,5,8,11-Tetraoxadodecane)

By formula: C6H14N+ + C8H18O4 = (C6H14N+ bullet C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar181.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Deltar183.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

(2,5,8,11-Tetraoxadodecane bullet 2Water) + Water = (2,5,8,11-Tetraoxadodecane bullet 3Water)

By formula: (C8H18O4 bullet 2H2O) + H2O = (C8H18O4 bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

(2,5,8,11-Tetraoxadodecane bullet 3Water) + Water = (2,5,8,11-Tetraoxadodecane bullet 4Water)

By formula: (C8H18O4 bullet 3H2O) + H2O = (C8H18O4 bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

(2,5,8,11-Tetraoxadodecane bullet Water) + Water = (2,5,8,11-Tetraoxadodecane bullet 2Water)

By formula: (C8H18O4 bullet H2O) + H2O = (C8H18O4 bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar51.5kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar133.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

C5H6N+ + 2,5,8,11-Tetraoxadodecane = (C5H6N+ bullet 2,5,8,11-Tetraoxadodecane)

By formula: C5H6N+ + C8H18O4 = (C5H6N+ bullet C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar145.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Deltar160.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

2,5,8,11-Tetraoxadodecane + Water = (2,5,8,11-Tetraoxadodecane bullet Water)

By formula: C8H18O4 + H2O = (C8H18O4 bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar85.4kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Deltar168.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1994
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S.; Duan, X., The Ionic Hydrogen Bond. 5. Polydentate and Solvent-Bridged Structures. Complexing of the Proton and the Hydronium Ions by Polyethers, J. Am. Chem. Soc., 1994, 116, 17, 7848, https://doi.org/10.1021/ja00096a047 . [all data]


Notes

Go To: Top, Reaction thermochemistry data, References