2,5,8,11-Tetraoxadodecane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil489.2KN/AWeast and Grasselli, 1989BS
Tboil489.KN/AHaertel, 1985Uncertainty assigned by TRC = 2. K; TRC
Tboil489.15KN/AAnonymous, 1982TRC
Tboil489.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Tfus228.15KN/AAnonymous, 1982TRC
Tfus228.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Ttriple229.3KN/ABeaumont, Clegg, et al., 1966Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Δvap63.7 ± 3.3kJ/molCGCNichols, Orf, et al., 2000AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
376.70.013Weast and Grasselli, 1989BS
376.60.013Buckingham and Donaghy, 1982BS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
23.71229.3Domalski and Hearing, 1996AC
23.715229.3Beaumont, Clegg, et al., 1966, 2DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
103.4229.3Beaumont, Clegg, et al., 1966, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H10N+ + 2,5,8,11-Tetraoxadodecane = (C3H10N+ • 2,5,8,11-Tetraoxadodecane)

By formula: C3H10N+ + C8H18O4 = (C3H10N+ • C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr145.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Δr167.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

C4H5N2+ + 2,5,8,11-Tetraoxadodecane = (C4H5N2+ • 2,5,8,11-Tetraoxadodecane)

By formula: C4H5N2+ + C8H18O4 = (C4H5N2+ • C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr155.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Δr173.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

C6H14N+ + 2,5,8,11-Tetraoxadodecane = (C6H14N+ • 2,5,8,11-Tetraoxadodecane)

By formula: C6H14N+ + C8H18O4 = (C6H14N+ • C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr181.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme
Quantity Value Units Method Reference Comment
Δr183.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; triglyme

(2,5,8,11-Tetraoxadodecane • 2Water) + Water = (2,5,8,11-Tetraoxadodecane • 3Water)

By formula: (C8H18O4 • 2H2O) + H2O = (C8H18O4 • 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

(2,5,8,11-Tetraoxadodecane • 3Water) + Water = (2,5,8,11-Tetraoxadodecane • 4Water)

By formula: (C8H18O4 • 3H2O) + H2O = (C8H18O4 • 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr38.kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

(2,5,8,11-Tetraoxadodecane • Water) + Water = (2,5,8,11-Tetraoxadodecane • 2Water)

By formula: (C8H18O4 • H2O) + H2O = (C8H18O4 • 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr133.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

C5H6N+ + 2,5,8,11-Tetraoxadodecane = (C5H6N+ • 2,5,8,11-Tetraoxadodecane)

By formula: C5H6N+ + C8H18O4 = (C5H6N+ • C8H18O4)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Δr145.kJ/molPHPMSMeot-Ner (Mautner), 1983gas phase
Quantity Value Units Method Reference Comment
Δr160.J/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase

2,5,8,11-Tetraoxadodecane + Water = (2,5,8,11-Tetraoxadodecane • Water)

By formula: C8H18O4 + H2O = (C8H18O4 • H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Δr85.4kJ/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase
Quantity Value Units Method Reference Comment
Δr168.J/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase

References

Go To: Top, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Haertel, 1985
Haertel, G.H., Low-volatility polar organic solvents for sulfur dioxide, hydrogen sulfide, and carbonyl sulfide., J. Chem. Eng. Data, 1985, 30, 57. [all data]

Anonymous, 1982
Anonymous, X., Glymes Grant Chemical, 1982, Baton Rouge, LA 1982. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Beaumont, Clegg, et al., 1966
Beaumont, R.H.; Clegg, B.; Gee, G.; Herbert, J.B.M.; Marks, D.J.; Roberts, R.C.; Sims, D., Heat Capacities of Propylene Oxide and of Some Polymers of Ethylene and Propylene Oxides, Polymer, 1966, 7, 401. [all data]

Nichols, Orf, et al., 2000
Nichols, Gary; Orf, Jennifer; Reiter, Sarah M.; Chickos, James; Gokel, George W., The vaporization enthalpies of some crown and polyethers by correlation gas chromatography, Thermochimica Acta, 2000, 346, 1-2, 15-28, https://doi.org/10.1016/S0040-6031(99)00405-0 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Beaumont, Clegg, et al., 1966, 2
Beaumont, R.H.; Clegg, B.; Gee, G.; Herbert, J.B.M.; Marks, D.J.; Roberts, R.C.; Sims, D., Heat capacities of propylene oxide and of some polymers of ethylene and propylene oxides, Polymer, 1966, 7, 401-416. [all data]

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1994
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S.; Duan, X., The Ionic Hydrogen Bond. 5. Polydentate and Solvent-Bridged Structures. Complexing of the Proton and the Hydronium Ions by Polyethers, J. Am. Chem. Soc., 1994, 116, 17, 7848, https://doi.org/10.1021/ja00096a047 . [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, References