1-Decanol

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-94. ± 3.kcal/molAVGN/AAverage of 6 values; Individual data points

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-114.3 ± 0.26kcal/molCcbMosselman and Dekker, 1975ALS
Δfliquid-114.66 ± 0.23kcal/molCcbChao and Rossini, 1965see Rossini, 1934; ALS
Δfliquid-116.18 ± 0.80kcal/molCcbGreen, 1960ALS
Δfliquid-116.2 ± 0.72kcal/molCcbVerkade and Coops, 1927estimated uncertainty; DRB
Quantity Value Units Method Reference Comment
Δcliquid-1582. ± 2.kcal/molCcbFreeman and Bagby, 1989Corresponding Δfliquid = -110. kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-1577.7 ± 0.26kcal/molCcbMosselman and Dekker, 1975Corresponding Δfliquid = -114.3 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-1577.35 ± 0.18kcal/molCcbChao and Rossini, 1965see Rossini, 1934; Corresponding Δfliquid = -114.63 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-1575.83 ± 0.80kcal/molCcbGreen, 1960Corresponding Δfliquid = -116.15 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-1575.8kcal/molCcbVerkade and Coops, 1927Corrected for 298 and 1 atm.; Corresponding Δfliquid = -116.2 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
89.144298.15Andreoli-Ball, Patterson, et al., 1988DH
92.69304.05Naziev and Bashirov, 1988T = 304 to 497 K. p = 0.1 MPa. Unsmoothed experimental datum given as 2.45 kJ/kg*K. Cp data given at pressures from 0.1 to 50 MPa.; DH
88.423298.15Costas and Patterson, 1985T = 283.15, 298.15, 313.15 K.; DH
90.30305.79Griigo'ev, Yanin, et al., 1979T = 305 to 463 K. p = 0.98 bar.; DH
90.1301.Svensson, 1979T = 301 to 461 K.; DH
90.177303.15Woycicka and Kalinowska, 1975DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H., Enthalpies of formation of n-alkan-1-ols, J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Rossini, 1934
Rossini, F.D., Heats of combustion and of formation of the normal aliphatic alcohols in the gaseous and liquid states, and the energies of their atomic linkages, J. Res. NBS, 1934, 13, 189-197. [all data]

Green, 1960
Green, J.H.S., Revision of the values of the heats of formation of normal alcohols, Chem. Ind. (London), 1960, 1215-1216. [all data]

Verkade and Coops, 1927
Verkade, P.E.; Coops, J., Jr., Calorimetric researches XIV. Heats of combustion of successive members of homologous series: the normal primary aliphatic alcohols, Recl. Trav. Chim. Pays-Bas, 1927, 46, 903-917. [all data]

Freeman and Bagby, 1989
Freeman, B.; Bagby, M.O., Heats of combustion of fatty esters and triglycerides, J. Am. Oil Chem. Soc., 1989, 66, 1601-1605. [all data]

Andreoli-Ball, Patterson, et al., 1988
Andreoli-Ball, L.; Patterson, D.; Costas, M.; Caceres-Alonso, M., Heat capacity and corresponding states in alkan-1-ol-n-alkane systems, J. Chem. Soc., Faraday Trans. 1, 1988, 84(11), 3991-4012. [all data]

Naziev and Bashirov, 1988
Naziev, Ya.M.; Bashirov, M.M., Isobaric specific heats of higher alcohols at elevated pressures, Teplofiz. Vysok. Temp., 1988, 26, 58-62. [all data]

Costas and Patterson, 1985
Costas, M.; Patterson, D., Self-association of alcohols in inert solvents, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 635-654. [all data]

Griigo'ev, Yanin, et al., 1979
Griigo'ev, B.A.; Yanin, G.S.; Rastorguev, Yu.L.; Thermophysical parameters of alcohols, Tr. GIAP, 54, 1979, 57-64. [all data]

Svensson, 1979
Svensson, Ch., Enthalpies of vaporization of 1-decanol and 1-dodecanol and their influence on the CH2-increment for the enthalpies of formation, J. Chem. Thermodynam., 1979, 11, 593-596. [all data]

Woycicka and Kalinowska, 1975
Woycicka, M.K.; Kalinowska, B., Enthalpies of mixing and excess heat capacities of dilute solutions of n-decanol with n-heptane and n-tridecane, Bull. Acad. Pol. Sci., Ser. Sci. Chim., 1975, 23, 759-764. [all data]


Notes

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