1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil539.7KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Δvap84.7 ± 0.3kJ/molGSEfimova, Emel'yanenko, et al., 2010Based on data from 338. to 373. K.; AC
Δvap75.6kJ/molTGAAfzal, Butt, et al., 1988Based on data from 294. to 325. K. See also Efimova, Emel'yanenko, et al., 2010.; AC
Δvap71.0 ± 2.6kJ/molN/ASivokova, Matejicek, et al., 1967Based on data from 431. to 492. K. See also Efimova, Emel'yanenko, et al., 2010.; AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
430.20.027Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
59.8446.AStephenson and Malanowski, 1987Based on data from 431. to 550. K. See also Dykyj, 1972.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1,2-Ethanediamine, N-(2-aminoethyl)- + Ethylenimine = 1,2-Ethanediamine, N,N'-bis(2-aminoethyl)-

By formula: C4H13N3 + C2H5N = C6H18N4

Quantity Value Units Method Reference Comment
Δr83.3 ± 4.2kJ/molCmDalin, Bobylev, et al., 1988liquid phase; solvent: Aqueous HCl; Kinetic

1,2-Ethanediamine, N,N'-bis(2-aminoethyl)- + Ethylenimine = Tetraethylenepentamine

By formula: C6H18N4 + C2H5N = C8H23N5

Quantity Value Units Method Reference Comment
Δr83.3 ± 4.6kJ/molCmDalin, Bobylev, et al., 1988liquid phase; solvent: Aqueous HCl; Kinetic

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Efimova, Emel'yanenko, et al., 2010
Efimova, Anastasia A.; Emel'yanenko, Vladimir N.; Verevkin, Sergey P.; Chernyak, Yury, Vapour pressure and enthalpy of vaporization of aliphatic poly-amines, The Journal of Chemical Thermodynamics, 2010, 42, 3, 330-336, https://doi.org/10.1016/j.jct.2009.09.003 . [all data]

Afzal, Butt, et al., 1988
Afzal, M.; Butt, P.K.; Iqbal, M.J., J. Sci. Ind. Res., 1988, 31, 404. [all data]

Sivokova, Matejicek, et al., 1967
Sivokova, M.; Matejicek, A.; Juracka, F., Chem. Prum., 1967, 17, 4, 213. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Dalin, Bobylev, et al., 1988
Dalin, A.R.; Bobylev, V.A.; Suslikov, V.F.; Kamskaya, O.I.; Tereshchenko, G.F., Nucleophilic cleavage and the formation of saturated heterocycles. VII. Kinetic and thermochemical study of reactions of aziridine with ethylene amines, J. Gen. Chem. USSR, 1988, 58, 1868-1871. [all data]


Notes

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