Acetamide, N-butyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference
236.89298.15Zegers, Roegschoten, et al., 1986
236.298.15Konicek and Wadso, 1971

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Acetic anhydride + 1-Butanamine = Acetamide, N-butyl- + Acetic acid

By formula: C4H6O3 + C4H11N = C6H13NO + C2H4O2

Quantity Value Units Method Reference Comment
Δr-113.2 ± 0.46kJ/molCmWadso, 1962liquid phase
Δr-163.7 ± 0.3kJ/molCmWadso, 1958liquid phase; Heat of aminolysis

Acetamide, N-butyl- + Acetic acid = Acetamide, N-acetyl-N-butyl- + Water

By formula: C6H13NO + C2H4O2 = C8H15NO2 + H2O

Quantity Value Units Method Reference Comment
Δr40.5 ± 0.50kJ/molCmWadso, 1965liquid phase; Heat of hydrolysis

1-Butanamine + Ethanethioic acid, S-butyl ester = 1-Butanethiol + Acetamide, N-butyl-

By formula: C4H11N + C6H12OS = C4H10S + C6H13NO

Quantity Value Units Method Reference Comment
Δr-57.74 ± 0.63kJ/molCmWadso, 1958liquid phase; Heat of aminolysis

1-Butanamine + 1-[1,2,4]Triazol-1-ylethanone = Acetamide, N-butyl- + 1H-1,2,4-Triazole

By formula: C4H11N + C4H5N3O = C6H13NO + C2H3N3

Quantity Value Units Method Reference Comment
Δr-85.8 ± 0.3kJ/molCmWadso, 1962solid phase

1-Butanamine + 1H-Imidazole, 1-acetyl- = Acetamide, N-butyl- + 1H-Imidazole

By formula: C4H11N + C5H6N2O = C6H13NO + C3H4N2

Quantity Value Units Method Reference Comment
Δr-75.6 ± 0.3kJ/molCmWadso, 1962solid phase

Acetamide, N-butyl- + Water = 1-Butanamine + Acetic acid

By formula: C6H13NO + H2O = C4H11N + C2H4O2

Quantity Value Units Method Reference Comment
Δr55.2 ± 0.2kJ/molCmWadso, 1962liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zegers, Roegschoten, et al., 1986
Zegers, H.C.; Roegschoten, R.; Mels, W.; Somsen, G., Flow calorimetry of viscous liquids. Volumes and heat capacities of mixtures of N,N-dimethylformamide with N-alkylacetamides, Can. J. Chem., 1986, 64, 40-45. [all data]

Konicek and Wadso, 1971
Konicek, J.; Wadso, I., Thermochemical properties of some carboxylic acids, amines and N-substituted amides in aqueous solution, Acta Chem. Scand., 1971, 25, 1541-1551. [all data]

Wadso, 1962
Wadso, I., Heats of aminolysis and hydrolysis of some N-acetyl compounds and of acetic anhydride, Acta Chem. Scand., 1962, 16, 471-478. [all data]

Wadso, 1958
Wadso, I., The heats of aminolysis of n-butyl thiolacetate and acetic anhydride, Acta Chem. Scand., 1958, 12, 635-640. [all data]

Wadso, 1965
Wadso, I., Thermochemical properties of diacetimide, N-butyldiacetimide and N-phenyldiacetimide, Acta Chem. Scand., 1965, 19, 1079-1087. [all data]


Notes

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