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1-Butanamine, N-butyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

C3H9Sn+ + 1-Butanamine, N-butyl- = (C3H9Sn+ bullet 1-Butanamine, N-butyl-)

By formula: C3H9Sn+ + C8H19N = (C3H9Sn+ bullet C8H19N)

Quantity Value Units Method Reference Comment
Deltar204.kJ/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar141.J/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
130.525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M

Benzene, 1-isocyanato-4-nitro- + 1-Butanamine, N-butyl- = C15H23N3O3

By formula: C7H4N2O3 + C8H19N = C15H23N3O3

Quantity Value Units Method Reference Comment
Deltar-113.6 ± 0.7kJ/molCmKiselev, Malkov, et al., 1989liquid phase; solvent: Dioxane; #TDE; ALS

1-Butanamine, N-butyl- + Benzene, 1-isocyanato-4-methyl- = C16H16N2O

By formula: C8H19N + C8H7NO = C16H16N2O

Quantity Value Units Method Reference Comment
Deltar-102.7 ± 0.8kJ/molCmKiselev, Malkov, et al., 1989liquid phase; solvent: Chlorobenzene; ALS

Hydrogen + 1-Butanamine, N-butylidene- = 1-Butanamine, N-butyl-

By formula: H2 + C8H17N = C8H19N

Quantity Value Units Method Reference Comment
Deltar86.2 ± 2.6kJ/molChydHafelinger and Steinmann, 1977liquid phase; solvent: Acetic acid; ALS

Benzene, isocyanato- + 1-Butanamine, N-butyl- = Urea, N,N-dibutyl-N'-phenyl-

By formula: C7H5NO + C8H19N = C15H24N2O

Quantity Value Units Method Reference Comment
Deltar-1088.8 ± 1.7kJ/molCmKiselev, Malkov, et al., 1989liquid phase; solvent: Dioxane; ALS

1-Butanamine, N-butyl- + Benzene, 1-isocyanato-3-methyl- = C16H26N2O

By formula: C8H19N + C8H7NO = C16H26N2O

Quantity Value Units Method Reference Comment
Deltar-103.3 ± 0.8kJ/molCmKiselev, Malkov, et al., 1989liquid phase; solvent: Dioxane; ALS

1-Butanamine, N-butyl- + Benzene, 1-isocyanato-2-methyl- = C16H26N2O

By formula: C8H19N + C8H7NO = C16H26N2O

Quantity Value Units Method Reference Comment
Deltar-96.1 ± 0.7kJ/molCmKiselev, Malkov, et al., 1989liquid phase; solvent: Dioxane; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stone and Splinter, 1984
Stone, J.A.; Splinter, D.E., A high-pressure mass spectrometric study of the binding of (CH3)3Sn+ to lewis bases in the gas phase, Int. J. Mass Spectrom. Ion Processes, 1984, 59, 169. [all data]

Kiselev, Malkov, et al., 1989
Kiselev, V.D.; Malkov, V.B.; Murzin, D.G.; Shakirov, I.M.; Konovalov, A.I., Thermochemical study of the reaction of isocyanate with amines, Dokl. Phys. Chem. (Engl. Transl.), 1989, 308, 711-713, In original 111. [all data]

Hafelinger and Steinmann, 1977
Hafelinger, G.; Steinmann, L., Heat of hydrogenation of compounds containing isolated and conjugted C=N bouble bonds, Angew. Chem. Int. Ed. Engl., 1977, 16, 47-48. [all data]


Notes

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